高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (12): 1845.

• 研究简报 • 上一篇    下一篇

叔丁醇氧化反应中Co－Mo－Te－O系催化剂结构与催化行为的研究

王国甲, 吴通好, 杨洪茂, 姜玉子, 嵇玉书   

  1. 吉林大学化学系, 长春, 130023
  • 收稿日期:1994-02-19 修回日期:1994-05-05 出版日期:1994-12-24 发布日期:1994-12-24
  • 通讯作者: 王国甲,男,54岁,副教授.
  • 作者简介:王国甲,男,54岁,副教授.
  • 基金资助:

    国家自然科学基金

The Structure and Catalytic Behaviour of Co-Mo-Te System in the Oxidation of tertButyl Alcohol

WANG Guo-Jia, WU Tong-Hao, YANG Hong-Mao, JIANG Yu-Zi, JI Yu-Shu   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1994-02-19 Revised:1994-05-05 Online:1994-12-24 Published:1994-12-24

PDF (PC)

关键词: Co－Mo－Te－O体系, 叔丁醇, 氧化

Abstract: The Co-Mo-Te system catalysts were prepared and chracterized by IRand XRD.The catalytic behaviour of Co-Mo-Te systems were studied in the tert-butyl alcohol oxidation reaction. The results indicate that the new phases of Co4TeMo3O16 and MoO3 are formed with introducing Te into Co-Mo systems.There exists some relationship between the conversion of tert-butyl alcohol, selectivity of oxidation products (MAL+MAAand Scox) and these new phases.

Key words: Co-Mo-Te-O systems, tert-butyl alcohol, Oxidation

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