高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (2): 292.

• 研究快报 • 上一篇    下一篇

2-皮考胺树脂的合成及对金和铂族离子的吸附性

胨伟国, 傅桂萍, 魏祥, 裘林红, 陈义镛   

  1. 杭州大学化学系, 杭州 310028
  • 收稿日期:1992-10-04 修回日期:1992-12-15 出版日期:1993-02-24 发布日期:1993-02-24
  • 通讯作者: 陈义镛
  • 基金资助:

    国家自然科学基金

Synthesis of 2-Picolyl Amine Resin and Its Sorption Properties for Gold and Platinum-Group Metal Ions

CHEN Wei-Guo, FU Gui-Ping, WEI Xiang, QTU Lin-Hong, CHEN Yi-Yong   

  1. Department of Chemistry, IIangzhalt University, Hangzhou, 310028
  • Received:1992-10-04 Revised:1992-12-15 Online:1993-02-24 Published:1993-02-24

PDF (PC)

被引次数

11

关键词: 2-皮考胺树脂, 铂族离子, 金, 吸附

Abstract: The functional group capacity of crosslinked macroporous polystyrene resin bearing 2-picolyl amine synthesized under optimum conditions is as high as 3.40 mmol/g resin.The influences of molar ratio of reagents, reaction temperature and reaction time on the nitrogen content of the resin were investigated.The sorption capacities of the resin for Au(Ⅲ), Ir(Ⅳ),Pt(Ⅳ),Pd(Ⅱ) and Rh (Ⅲ) are 768.0, 384.8, 356.0, 167.2, and 110.5 mg/g resin, respectively.The coordination ratio of AuCl4- ; IrClAuCl62-, PtClAuCl62-, PdClAuCl42-; and RHClAuCl63- are 1.15; 0.59, 0.54, 0.46 and 0.32, respectively.The distribution coefficients of the resin for Au(Ⅲ), Rh(Ⅱ) and Ir(Ⅳ) are 1.1×104, 2.6 ×103, and 1.9×103 mol/L, respectively.

Key words: 2-Picolyl amine resin, Platinum-group ions, Gold, Sorption

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