高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (4): 490.

• 论文 • 上一篇    下一篇

过硼酸钠选择氧化苯硫基乙酸酯的研究

徐小青, 周卫清, 张正   

  1. 南京大学化学系, 南京, 210008
  • 收稿日期:1991-04-27 出版日期:1992-04-24 发布日期:1992-04-24
  • 通讯作者: 张正

Selective Oxidation of Phenylthioacetates to Phenylsulfinylacetates with Sodium Perborate

XU Xiao-qing, ZHOU Wei-qing, ZHANG Zheng   

  1. Department of Chemistry, Nanjing University, Nanjing, 210008
  • Received:1991-04-27 Online:1992-04-24 Published:1992-04-24

关键词: 过硼酸钠, 氧化, 苯硫基乙酸酯, 苯亚磺酰基乙酸酯

Abstract: Ten phenylsulfinyl acetates were obtained by the selective oxidation of the corresponding sulfides with sodium perborate (NaBO3 · 4H2O) in acetic acid at 50~55℃.The present method has the following advantages: 1.mild conditions are employed; 2.normally over oxidation is not observed; 3.the reagent is readily available and can be safely handled; 4.excellent yields are obtained.

Key words: Sodium perborate, Oxidation, Phenylthioacetate, Phenylsulfinylacetate

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