高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (2): 173.

• 研究论文 •    下一篇

聚2-对丙烯酰氧苯基-5,10,15,20-四苯基卟啉镍的合成

李平英, 黄齐茂, 陈彰评, 马舒翼, 徐汉生   

  1. 武汉大学化学系, 武汉 430072
  • 收稿日期:2001-03-22 出版日期:2002-02-24 发布日期:2002-02-24
  • 通讯作者: 李平英(1947年出生),女,副教授,从事卟啉化合物的合成研究.E-mail:CHENZP@Chem.wnu.edu.cn E-mail:CHENZP@Chem.wnu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29872033)资助

Synthesis of 2-(p-Propenoyloxyphenyl)-5,10,15,20- tetraphenylporphyrin Nickel Polymer

LI Ping-Ying, HUANG Qi-Mao, CHEN Zhang-Ping, MA Shu-Yi, Xu Han-Sheng   

  1. Department of Chemistry, Wuhan University, Wuhan 430072, China
  • Received:2001-03-22 Online:2002-02-24 Published:2002-02-24

摘要: 2-对羟基苯基-5,10,15,20-四苯基卟啉镍(Ⅰ)和2-邻羟基苯基-5,10,15,20-四苯基卟啉镍(Ⅰ′)分别与丙烯酰氯反应,生成了2-对丙烯酰氧苯基-5,10,15,20-四苯基卟啉镍(Ⅱ)和2-邻丙烯酰氧苯基-5,10,15,20-四苯基卟啉镍(Ⅱ′),在引发剂作用下,前者聚合生成了聚2-对丙烯酰氧苯基-5,10,15,20-四苯基卟啉镍(Ⅲ).通过元素分析、红外光谱、紫外-可见光谱、核磁共振谱和质谱对单体和聚合物的结构进行了表征.

关键词: 合成, 卟啉, 单体, 聚合物

Abstract: 2-(p-propenoyloxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅱ) and 2-(o-propenoy-loxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅱ′) was synthesized from acryoyl chloride with 2 (p hydroxyphenyl)5,10,15,20 tetraphenylporphyrin nickel(Ⅰ) and 2-(o-hydroxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅰ′) correspondingly. Compound (Ⅱ) was further polymerized to 2-(p-propenoyloxyphenyl)-5,10,15,20-tetraphenylporphyrin nickel(Ⅲ) in the presence of initiator. Their chemical structures were identified by NMR, UV-Vis, IR and MS spectra, as well as elemental analysis.

Key words: Synthesis, Porphyrin, Monomer, Polymer

中图分类号: 

TrendMD: