高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (1): 75.

• 研究简报 • 上一篇    下一篇

单波长可见光照射下二氧化碳羰基化反应研究

庄建勤1, 尹静梅2, 高大彬2, 郑学仿2, 周广运2, 周宁章2, 王祥生3, 郭新闻3   

  1. 1. 中国科学院大连化学物理研究所, 大连 116023;
    2. 大连大学化学化工系, 大连 116622;
    3. 教育部大连理工大学碳资源综合利用开放实验室, 大连 116012
  • 收稿日期:2000-01-03 出版日期:2001-01-24 发布日期:2001-01-24
  • 通讯作者: 高大彬(1961年出生),男,博士,教授,从事光催化羰基化反应研究.
  • 基金资助:

    辽宁省自然科学基金(批准号:962052);教育部大连理工大学碳资源综合利用开放实验室资助(批准号:97007K)

Studies on the Carbonylation of Carbon Dioxide Under Single Wavelength Visible Light Irradiation

ZHUANG Jian-Qin1, YIN Jing-Mei2, GAO Da-Bin2, ZHENG Xue-Fang2, ZHOU Guang-Yun2, ZHOU Ning-Zhang2, WANG Xiang-Sheng3, GUO Xin-Wen3   

  1. 1. Dalian Instituteof Chemical Physics, The Chinese Academyof Science, Dalian 116023, China;
    2. Department of Chemistry & Chemical Engineering, Dalian University, Dalian 116622, China;
    3. Educational Ministry Open Laboratory of Carbon Resource Utilization, Dalian University of Technology, Dalian 116012, China
  • Received:2000-01-03 Online:2001-01-24 Published:2001-01-24

PDF (PC)

被引次数

2

关键词: 单波长, 可见光, 二氧化碳, 羰基化反应

Abstract: It is the first time to report the carbonylation of cyclohexene with carbon dioxide under ambient conditions irradiated at single wavelength visible light.The effects of catalysts, the additives and different wavelength have been investigated, which indicated that the metal complexes such as CoTPPand MnTPPacted as catalyst of the carbonylation as well as sensitizer under the irradiation of special wavelength visible light. Furthermore, when adding sodium proponiate to the solution, the catalysts such as PCFe would be activated and the formation of ester was promoted obviously. We also detected the quantum yield of this reaction, and found it can reach to 10-2. As far as the quantum yield and taking good advantage of the energy from solar was concerned. HSO3PCCo was the better catalyst for the carbonylation.

Key words: Single wavelength, Visible light, Carbon dioxide, Carbonylation

中图分类号: 

TrendMD: