高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (5): 725.

• 论文 • 上一篇    下一篇

扩展的共轭二价阴离子四硫富瓦烯四硫桥双金属配合物的合成与性质

王建华, 杨更新, 迟兴宝, 王小刚   

  1. 西北大学化学系, 西安 710069
  • 收稿日期:1999-04-20 出版日期:2000-05-24 发布日期:2000-05-24
  • 通讯作者: 王建华(1939年出生),男,教授,博士生导师,从事有机化学研究.
  • 基金资助:

    陕西省自然科学基金(批准号:96H07)

Synthesis and Properties of Extensively Conjugated Dianionic Tetrathiafulvalene Tetrathiolate-Bridged Bimetal Complexes

WANG Jian-Hua, YANG Geng-Xin, CHI Xing-Bao, WANG Xiao-Gang   

  1. Department of Chemistry, Northwest University, Xi'an 710069, China
  • Received:1999-04-20 Online:2000-05-24 Published:2000-05-24

摘要: 合成4种新的扩展的共轭二价阴离子四硫富瓦烯四硫桥双金属配合物和2种四硫富瓦烯四硫多金属低聚物,对双金属配合物的UV-Vis谱和循环伏安图进行了研究,测定了双金属配合物及低聚物的电导率。

关键词: 四硫富瓦烯四硫桥双金属配合物, 合成, UV-Vis光谱, 循环伏安图, 电导率

Abstract: Four new extensively conjugated dianionic tetrathiafulvalene tetrathiolate-bridged bimetal complexes and two tetrathiafulvalene tetrathiolate multimetal oligomers were synthesized in this paper. UV-Vis spectra and cyclic-voltammograms of the four complexes were studied. The conductivity of these complexes and oligommers were given too.

Key words: Tetrathiafulvalene tetrathiolate-bridged bimetal complexes, Synthesis, UV-Vis spectra, Cyclic voltammograms, Conductivity

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