高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (6): 939.

• 论文 • 上一篇    下一篇

钴(Ⅱ)邻菲咯啉、8-羟基喹啉配合物/Y型分子筛的制备、表征及催化苯酚羟化的研究

齐兴义1, 王国甲1, 叶兴凯2, 吴越2   

  1. 1. 吉林大学化学系, 长春 130023;
    2. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1995-06-07 出版日期:1996-06-24 发布日期:1996-06-24
  • 通讯作者: 吴越
  • 作者简介:齐兴义,男,39岁,博士后(大连化学物理研究所).
  • 基金资助:

    国家自然科学基金

Studies on Preparation,Characterization of Cobalt(Ⅱ) Phenanthroline and 8-Hydroxyquinoline Complexes/Y Zeolite,and Catalytic Hydroxylation of Phenol

QI Xmg-Yi1, WANG Guo-Jia1, YIE Xing-Kai2, WU Yue2   

  1. 1. Department of Chemistry, Jilin University, Changchun 130023;
    2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1995-06-07 Online:1996-06-24 Published:1996-06-24

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被引次数

12

摘要： 制备了钴(Ⅱ)邻菲咯啉、8-羟基喹啉配合物/Y型分子筛;利用元素分析、TG-DTA、SEM、UV-Vis、BET及XRD等方法确定了分子筛笼中金属配合物的生成及其晶体结构;考察了实验参数对苯酚转化率及产物选择性的影响。

关键词: 邻菲咯啉, 8-羟基喹啉, 分子筛, 苯酚羟化

Abstract: Cobal(Ⅱ) phenanthroline and 8-hydroxyquinoline complexes/Yzeolite,denoted as CoPhen/Yand CoOx/Yrespectively,were prepared.The formation of the metal complexes mentioned above within the cages of Yzeolite and their crystal structures were determined by elementary analyses,TG-DTA,diffuse reflectance UV-Vis,SEM,BETand XRDmethods.The influence of experimental parameters upon phenol conversion and product selectivities was investigated as well.

Key words: Phenanthroline, 8-Hydroxyquinoline, Zeolite, Phenol hydroxylation

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