高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (5): 537.

• 研究简报 • 上一篇    下一篇

毛莨甙的合成

王鍾麒1, 陈忆2, 伍越环2, 朱胄远2   

  1. 1. 中国科学院上海有机化学研究所;
    2. 中国科学技术大学近代化学系
  • 收稿日期:1989-01-04 出版日期:1990-05-24 发布日期:1990-05-24
  • 通讯作者: 伍越环

Synthesis of Ranunculin

Wang Zhongqi1, Chen Yi2, Wu Yuehuan2, Zhu Zhouyuan2   

  1. 1. Shanghai Institute of Organic Chemistry, Academia Sirica, Shanghai;
    2. The Department of Modem Chemistry, University of Science and Technology of China Hefei
  • Received:1989-01-04 Online:1990-05-24 Published:1990-05-24

摘要: 毛莨科(Ranunculaceae)植物的提取液对多种农业害虫如:稻螟、棉蚜、玉米螟、菜青虫和地老虎等有较好的杀虫效果,对小麦和土豆等蓿菌孢子的发芽有抑制作用[1],Hill等从这种植物中分离到毛莨甙(Ranunculin)1,本身无生物活性,而是由于它进入生物体内经酶解成原白头翁素(Protoanemnin)[2,3]. 2而发生作用的。2很不稳定,容易二聚成白头翁素(Anemonin)3而失去活性。

关键词: 毛莨甙, 原白头翁素, L-谷氨酸, 合成

Abstract: This article reports that main intermediate (S)-4-triphenylmethoxymethyl-Δ2-butenolide (4d) is produced from L-giutamic acid through four step reactions and target Ranunculin(1) is obtained by the known methods after 4d turn into (S)-4-hydroxymethyl-Δ2-butenolide (4a).

Key words: Ranunculin, Protoanemonin, L-Glutamic acid, Synthesis

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