高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (1): 6.

• 研究论文 • 上一篇    下一篇

锡(Ⅳ)、钯(Ⅱ)、金(Ⅲ)与二(2-乙基己基)亚砜配合物的研究

王汉章, 刘国兴, 朱沁华, 陆忠娥   

  1. 苏州大学化学系
  • 收稿日期:1987-07-18 出版日期:1989-01-24 发布日期:1989-01-24

Studies on the Complexes of Sn (Ⅳ), Pd (Ⅱ) and Au (Ⅲ) with Di(2-Ethylhexyl) Sulfoxide

Wang Hanzhang, Liu Guoxing, Zhu Qinhua, Lu Zhonge   

  1. Department of Chemistry Suzhou University, Suzhou
  • Received:1987-07-18 Online:1989-01-24 Published:1989-01-24

摘要: 合成了长碳链的二(2-乙基己基)亚砜与锡(Ⅳ)、钯(Ⅱ)、金(Ⅲ)的配合物,通过组成分析、摩尔电导的测定及红外、紫外图谱的研究,确定了配合物的组成,推断了配合物的结构。

关键词: 锡, 钯, 金, 二(2-乙基己基)亚砜

Abstract: The complexes of tin (Ⅳ), palladium (Ⅱ) and gold(Ⅲ) with di(2-ethylhexyl) sulfoxide (DEHSO) were synthesized in hydrocholoric acid medium. The compositions and the structures of Sn (DEHSO)2Cl4, (PdCl2DEHSO)2,H3O(DEHSO)3AuCl4are inferred by elemental analysis, molar conductance, IR and UV spectra.

Key words: Sn(Ⅳ),Pd(Ⅱ),Au(Ⅲ), Di(2-ethylhexyl)sulfoxide complexes

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