高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (11): 2393-2403.doi: 10.7503/cjcu20200427

• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇    下一篇

多相催化剂催化二氧化碳加氢合成甲醇的研究进展

王艳燕1,2, 刘会贞1,2(), 韩布兴1,2()   

  1. 1.中国科学院化学研究所, 北京分子科学国家实验室, 中国科学院胶体界面与热力学重点实验室, 北京 100190
    2.中国科学院大学化学科学学院, 北京 100049
  • 收稿日期:2020-07-06 出版日期:2020-11-10 发布日期:2020-11-06
  • 通讯作者: 刘会贞 E-mail:liuhz@iccas.ac.cn;hanbx@iccas.ac.cn
  • 作者简介:韩布兴, 男, 博士, 研究员, 中国科学院院士, 主要从事生物质及Cl资源转化利用方面的研究. E-mail: hanbx@iccas.ac.cn
  • 基金资助:
    国家重点研发计划(2018YFB0605801)

Advances in CO2 Hydrogenation to Methanol by Heterogeneous Catalysis

WANG Yanyan1,2, LIU Huizhen1,2(), HAN Buxing1,2()   

  1. 1.Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Colloid and Interface and Thermodynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China
    2.School of Chemical Science,University of Chinese Academy of Sciences,Beijing 100049,China
  • Received:2020-07-06 Online:2020-11-10 Published:2020-11-06
  • Contact: LIU Huizhen E-mail:liuhz@iccas.ac.cn;hanbx@iccas.ac.cn
  • Supported by:
    Supported by the National Key Research and Development Project of China(2018YFB0605801)

摘要:

近年来, 随着空气中二氧化碳含量的不断升高, 二氧化碳的催化转化在科研界和工业界受到了广泛关注. 非均相催化的二氧化碳加氢合成甲醇是实现二氧化碳资源化利用的重要手段之一, 具有良好的应用前景. 本文系统概述了非均相催化二氧化碳加氢合成甲醇反应的近期研究进展, 重点介绍了金属催化剂和金属氧化物催化剂, 对反应机理进行了阐述, 并对该领域仍待解决的问题和发展前景进行了展望.

关键词: 二氧化碳, 甲醇, 非均相催化

Abstract:

In recent years, with the gradually increased content of carbon dioxide in air, the catalytic conversion of CO2 has attracted broad attention in scientific and industrial community. CO2 hydrogenation to methanol by heterogeneous catalysis is one of the most important means to realize the utilization of CO2, which has a promising application prospect. In this review, we outline recent advances in CO2 hydrogenation to methanol by heterogeneous catalysis and focus on widely studied metal and metal oxide catalysts. Besides, we give a brief introduction to the reaction mechanism. Finally, we provide the challenges and opportunities in this area.

Key words: Carbon dioxide, Methanol, Heterogeneous catalysis

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