Synthesis of Tetrathiafulvalene-calixarene Derivatives and Their  Intermolecular Electron Transfer Towards Tetrachloro-1,4-benzoquinone

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 2103.

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Synthesis of Tetrathiafulvalene-calixarene Derivatives and Their Intermolecular Electron Transfer Towards Tetrachloro-1,4-benzoquinone

ZHAO Bang-Tun^1*, LIU Lian-Wei², DING Jing-Jing², QU Gui-Rong²

1. Department of Chemistry, Luoyang Normal University, Luoyang 471022, China;
2. College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China

Received:2011-03-31 Revised:2011-06-12 Online:2011-09-10 Published:2011-08-11
Contact: ZHAO Bang-Tun E-mail:zbt@lynu.edu.cn
Supported by:
国家自然科学基金(批准号: 20872058)资助.

Abstract

Abstract: Two ether-linked tetrathiafulvalene-calixarene derivatives were designed and synthesized，and their chemical structures were characterized by 1H-NMR, 13C-NMR, FAB Mass spectra and IR. Their electrochemical properties have been investigated using cyclic voltammetry method. And UV-Vis spectra was used to exploit the intermolecular electron transfer between the target compound (4a, 4b) and tetrachloro-1,4-benzoquinone (Q) regulated by metal ions (Na+, K+, Ba2+). The results the K+ may effectively promoted the electron transfer between 4b and Q system.

Key words: Tetrathiafulvalene, Calixarene, Cyclic voltammetry, Intermolecular electron transfer

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ZHAO Bang-Tun*, LIU Lian-Wei, DING Jing-Jing, QU Gui-Rong. Synthesis of Tetrathiafulvalene-calixarene Derivatives and Their Intermolecular Electron Transfer Towards Tetrachloro-1,4-benzoquinone[J]. Chem. J. Chinese Universities, 2011, 32(9): 2103.

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Synthesis of Tetrathiafulvalene-calixarene Derivatives and Their Intermolecular Electron Transfer Towards Tetrachloro-1,4-benzoquinone

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