Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (2): 235.

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Conductivity and CO Methanation Activity of LaNiO3

SHEN Yue-nian1, HU Rui-sheng1, LIU Xin-hua1, HUANG Wen-de1, SHENG Shi-shan2   

  1. 1. Department of Chemistry, Inner Mongolia University, Hohhot, 010021;
    2. State Key Laboratory for Catalysis, Delian Institute of Chemical Physics, Chinese Academy of Sciences
  • Received:1991-02-09 Online:1992-02-24 Published:1992-02-24

Abstract: In this paper, the single phase of polycrystal perovskite-type oxide, LaNiO3, which was prepared by decomposition of nitrates at 800℃, was characterized by X-ray diffractionThe resistivity of LaNiO3 was measuredIt was found that the resistivity of LaNiO3 was lower than that of the mixed oxides of La and Ni, but higher than that of metal nickelIt was suggested that LaNiO3 is a semi-metalThe activity order for catalysing COmethanation is metal nickel> LaNiO3>NiO, which corresponds to that of their conductivities and their localized degree of d electrons in nickel atoms or ions.

Key words: LaNiO3, Conductivity, CO rnethanation

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