Fe3O4@Au核-壳纳米复合材料的制备及对农药福美双的SERS检测研究

doi:10.7503/cjcu20190183

高等学校化学学报 ›› 2019, Vol. 40 ›› Issue (10): 2067.doi: 10.7503/cjcu20190183

Fe₃O₄@Au核-壳纳米复合材料的制备及对农药福美双的SERS检测研究

韩东来^1,²,李博珣²,杨硕^1,³,闫永胜¹,杨丽丽^1,⁴,刘洋^4,^*(),李春香¹

^1. 江苏大学绿色化学与化工技术研究院, 镇江 212013
^2. 长春理工大学材料科学与工程学院, 长春 130022
^3. 长春光学精密机械与物理研究所, 长春 130033
^4. 吉林师范大学功能材料物理与化学实验室, 四平 136000

收稿日期:2019-03-27 出版日期:2019-10-08 发布日期:2019-08-20
通讯作者: 刘洋 E-mail:liuyang@jlnu.edu.cn
基金资助:
国家自然科学基金(Nos.21676115);国家自然科学基金(Nos.61705020);中国博士后科学基金(No.2017M621645);江苏省博士后基金(Nos.1701103B);江苏省博士后基金(Nos.1701106B);江苏省自然科学基金(No.BK20180880)

Facile Synthesis of Fe₃O₄@Au Core-shell Nanocomposites as an SERS Substrate for the Detection of Thiram ^†

HAN Donglai^1,²,LI Boxun²,YANG Shuo^1,³,YAN Yongsheng¹,YANG Lili^1,⁴,LIU Yang^4,^*(),LI Chunxiang¹

^1. School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, China;
^2. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China
^3. Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China
^4. Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000, China

Received:2019-03-27 Online:2019-10-08 Published:2019-08-20
Contact: LIU Yang E-mail:liuyang@jlnu.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.21676115);† Supported by the National Natural Science Foundation of China(Nos.61705020);the Postdoctoral Science Foundation of China(No.2017M621645);the Postdoctoral Fund of Jiangsu Province, China(Nos.1701103B);the Postdoctoral Fund of Jiangsu Province, China(Nos.1701106B);the Natural Science Foundation of Jiangsu Province, China.(No.BK20180880)

摘要/Abstract

摘要：

首先采用热分解法制备了Fe₃O₄纳米材料, 再将其作为磁性核, 分别采用种子沉积法和种子介导生长法制备了Fe₃O₄-Au核-卫星纳米复合材料和Fe₃O₄@Au核-壳纳米复合材料, 并对其形貌和性能进行了表征分析. 结果表明, 所制备的Fe₃O₄-Au核-卫星和Fe₃O₄@Au核-壳纳米复合材料粒径均匀, Au纳米颗粒均匀沉积/包覆在Fe₃O₄纳米材料表面, 且样品均具有良好的磁响应性. 使用4-氨基苯硫酚(4-ATP)作为拉曼探针分子, 对比了这两种纳米复合材料作为SERS基底时的拉曼信号增强效果. 结果显示, Fe₃O₄@Au核-壳纳米复合材料是更优秀的SERS基底, 且该SERS基底具有良好的信号再现性. 最后, 使用Fe₃O₄@Au核-壳纳米复合材料作为SERS基底, 成功地在苹果皮上检测出残留福美双的SERS信号.

关键词: 四氧化三铁, 金, 核-壳纳米复合材料, 表面增强拉曼光谱(SERS), 福美双

Abstract:

Fe₃O₄ nanomaterial was prepared by thermal decomposition method, and then Fe₃O₄-Au core-satellite nanocomposites and Fe₃O₄@Au core-shell nanocomposites were prepared by seed deposition method and seed-mediated growth method, respectively. The morphology of the Fe₃O₄-Au core-satellite nanocompo-sites and Fe₃O₄@Au core-shell nanocomposites were uniform and the Au nanoparticles were uniformly deposited/coated on the surface of Fe₃O₄ nanomaterials. The samples had good magnetic responsiveness. Using 4-aminothiophenol(4-ATP) as Raman probe molecule, the Raman signal enhancement effect of the two nanocomposites as SERS substrates was compared. The results showed that the Fe₃O₄@Au core-shell nanocompo-site was a better SERS substrate, and had good signal reproducibility. Finally, using Fe₃O₄@Au core-shell nanocomposite as SERS substrate, the SERS signal of the residual thiram was detected on the apple peel successfully.

Key words: Fe₃O₄, Au, Core-shell nanocomposites, Surface enhanced Raman scattering(SERS), Thriam

中图分类号:

O611

TrendMD:

韩东来,李博珣,杨硕,闫永胜,杨丽丽,刘洋,李春香. Fe₃O₄@Au核-壳纳米复合材料的制备及对农药福美双的SERS检测研究. 高等学校化学学报, 2019, 40(10): 2067.

HAN Donglai,LI Boxun,YANG Shuo,YAN Yongsheng,YANG Lili,LIU Yang,LI Chunxiang. Facile Synthesis of Fe₃O₄@Au Core-shell Nanocomposites as an SERS Substrate for the Detection of Thiram ^†. Chem. J. Chinese Universities, 2019, 40(10): 2067.

图/表 10

Scheme 1 Schematic illustration of the synthesis process of Fe3O4@Au core-shell nanocomposites and their application in detecting the cycle of 4-ATP by SERS

Fig.1 XRD patterns of the prepared Fe3O4(a), Fe3O4-Au(b) and Fe3O4@Au(c)

Fig.2 Survey XPS spectra(A) and high resolution XPS spectra of Au 4f(B) of the prepared Fe3O4, Fe3O4-Au, and Fe3O4@Au

Fig.3 SEM images of the prepared Fe3O4 nanoparticles(A), Fe3O4-Au core-satellite nanocomposites(B) and Fe3O4@Au core-shell nanocomposites(C)

Fig.4 TEM images of Fe3O4 nanoparticles(A), Fe3O4-Au core-satellite nanocomposites(B) and Fe3O4@Au core-shell nanocomposites(C)

Fig.5 UV-Vis spectra of the gold sol(a), Fe3O4 nanoparticles(b), Fe3O4-Au core-satellite nanocomposites(c) and Fe3O4@Au core-shell nanocomposites(d)

Fig.6 M-H loops of Fe3O4 nanoparticles(a), Fe3O4-Au core-satellite nanocomposites(b) and Fe3O4@Au core-shell nanocomposites(c)

Fig.7 SERS spectra of 1×10-3 mol/L 4-ATP on Fe3O4@Au core-shell nanocomposites and Fe3O4-Au core-satellite nanocomposites(A) and SERS spectra of 10 cycles on Fe3O4@Au core-shell nano-composites(B)

Scheme 2 Illustration of Fe3O4@Au core-shell nanocomposites being used as an SERS substrate to detect the residual thiram on the surface of apple peel

Fig.8 SERS spectrum of thiram detected on apple peel with Fe3O4@Au core-shell nanocomposite as substrate

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Fe₃O₄@Au核-壳纳米复合材料的制备及对农药福美双的SERS检测研究

Facile Synthesis of Fe₃O₄@Au Core-shell Nanocomposites as an SERS Substrate for the Detection of Thiram ^†

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