高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (1): 196.

• 研究论文 • 上一篇    

含钛苯乙烯单体及其聚合物的合成与表征

杨红领1,张晟1,臧一波1,朱方华2,张林2,陈学太1   

  1. 1. 南京大学化学化工学院, 配位化学国家重点实验室,  南京 210093;
    2. 中国工程物理研究院激光聚变研究中心, 绵阳 621900
  • 收稿日期:2010-02-09 修回日期:2010-09-06 出版日期:2011-01-10 发布日期:2010-12-11
  • 通讯作者: 陈学太 E-mail:xtchen@netra.nju.edu.cn
  • 基金资助:

    国家自然科学基金委员会-中国工程物理研究院联合基金(批准号: 10676012)资助.

Synthesis and Characterization of Titanium\|containing Styrene Monomer and Polymer

YANG Hong-Ling1, ZHANG Sheng1, ZANG Yi-Bo1, ZHU Fang-Hua2, ZHANG Lin2, CHEN Xue-Tai1*   

  1. 1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
    2. Research Centre of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2010-02-09 Revised:2010-09-06 Online:2011-01-10 Published:2010-12-11
  • Contact: Chen Xue-tai E-mail:xtchen@netra.nju.edu.cn
  • Supported by:

    国家自然科学基金委员会-中国工程物理研究院联合基金(批准号: 10676012)资助.

摘要: 合成并表征了含2,6吡啶二羧酸根二茂钛基团的苯乙烯单体。通过该含钛单体与苯乙烯的溶液共聚反应得到了稳定性高且可溶的共聚物。所得的共聚物能溶于THF, CH2Cl2和甲苯中,其玻璃化转变温度为106 oC。该含钛聚苯乙烯有望应用于惯性约束聚变(ICF)实验靶用聚合物微球的制备。

关键词: 钛, 苯乙烯, 共聚, 合成

Abstract: A styrenic monomer containing dicylopentadienyltitanium group and 2,6-pyridinedicarboxylate has been synthesized and fully characterized. A stable and soluble copolymer was obtained by the solution copolymerization reaction between the titanium-containing monomer and styrene. This copolymer was found to be soluble in THF, CH2Cl2 and toluene and exhibit a glass transition temperature of 106 oC. This titanium-containing polystyrene could be used in the fabrication of the micro-spheres for the ICF experiments.

Key words: Titanium, Styrene, Copolymerization, Synthesis

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