高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (7): 1204.

• 研究论文 • 上一篇    下一篇

新型桥连双卟啉化合物的合成及结构表征

付世涛, 王凯, 谢征, 李早英   

  1. 武汉大学化学与分子科学学院, 武汉 430072
  • 收稿日期:2003-08-19 出版日期:2004-07-24 发布日期:2004-07-24
  • 通讯作者: 李早英(1949年出生),女,博士,教授,博士生导师,从事卟啉化学研究.E-mail:zyliwuc@whu.edu.cn E-mail:zyliwuc@whu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29972035)资助

Synthesis and Characterization of Novel Bridged Porphyrin Dimers

FU Shi-Tao, WANG Kai, XIE Zheng, LI Zao-Ying   

  1. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
  • Received:2003-08-19 Online:2004-07-24 Published:2004-07-24

摘要: 通过将4,4′-二羧基-2,2′-联吡啶、2,6-二溴甲基吡啶、2,6-二羟甲基吡啶和1,8-二氨基萘分别与5-(4-羟基苯基)-10,15,20-三苯基卟啉(1a)、5-(4-甲酰苯基)-10,15,20-三苯基卟啉(1b)和5-[4-(4′-溴代丁氧基)苯基]-10,15,20-三苯基卟啉(1c)反应,合成了3类新型的双卟啉化合物2a—2e,经IR,1HNMR,MS,UV-Vis光谱及元素分析对中间体和目标化合物的结构进行了表征.

关键词: 双卟啉化合物, 合成, 结构表征

Abstract: Reaction of 4,4′-dicarboxy-2,2′-bipyridine, 2,6-dibromomethyl pyridine, 2,6-dihydro-xymethyl pyridine and 1,8-diaminonaphthalene with 5-(4-hydroxyphenyl)-10,15,20-triphenyl porphyrin, 5-(4-chloroformacylphenyl)-10,15,20-triphenyl porphyrin and 5-[4-(4′-bromobutoxy)phenyl]-10,15,20-triphenyl porphyrin gave three types bridged diporphyrins 2a-2e, respectively. These intermediates and novel compounds were confirmed by IR, 1H NMR, MS, UV-Vis and elemental analysis.

Key words: Porphyrin dimers, Synthesis, Structure characterization

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