高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (2): 185.

• 研究简报 • 上一篇    下一篇

η2C70[RhCl(CO)(PPh3)2]n配合物的合成和表征

杨森根, 唐田, 林永生, 程大典, 詹梦熊, 郑兰荪   

  1. 厦门大学化学系, 厦门 361005
  • 收稿日期:2000-02-21 出版日期:2001-02-24 发布日期:2001-02-24
  • 通讯作者: 郑兰荪(1954年出生),男,博士,博士生导师,从事原子簇化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29471024);高等学校博士学科点专项科研基金(批准号:98038410)资助

Synthesis and Characterization for Complexesη2-C70[RhCl(CO)(PPh3)2]n

YANG Sen-Gen, TANG Tian, LIN Yong-Sheng, CHENG Da-Dian, ZHAN Meng-Xiong, ZHENG Lan-Sun   

  1. Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received:2000-02-21 Online:2001-02-24 Published:2001-02-24

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关键词: C70[RhCl(CO)(PPh3)2]2, C70[RhCl(CO)(PPh3)2], 合成, 表征

Abstract: The fullerene complexes, η2-C7Ox[RhCl(CO)(PPh3)2]n(n=1, 2), have been prepared by the reaction of C70 with RhCl(CO)(PPh3)2 in methylbenzene at room temperature. The new complexes were characterized by UV-Vis spectra, IR, XPSand elemental analysis. The results show that the complexes of η2 form can be formed by RhCl(CO)(PPh3)2 bonding to C70 in theσ-π way. In addition, the complexes structures have been supposed.

Key words: C70[RhCl(CO)(PPh3)2]2, C70[RhCl(CO)(PPh3)2], Synthesis, Characterization

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