高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (5): 789.

• 研究快报 • 上一篇    下一篇

脉冲激光溅射合成全氯代多环芳烃

周异男, 谢素原, 陈宏, 黄荣彬, 郑兰荪   

  1. 厦门大学化学系, 固体表面物理化学国家重点实验室, 厦门 361005
  • 收稿日期:1999-07-17 出版日期:2000-05-24 发布日期:2000-05-24
  • 通讯作者: 郑兰荪(1954年出生),男,博士,博士生导师,从事原子簇化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29890210)

Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation

ZHOU Yi-Nan, XIE Su-Yuan, CHEN Hong, HUANG Rong-Bin, ZHENG Lan-Sun   

  1. Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, China
  • Received:1999-07-17 Online:2000-05-24 Published:2000-05-24

PDF (PC)

被引次数

6

关键词: 激光溅射, 合成, 全氯代多环芳烃

Abstract: By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C6Cl6), octachloronaphthalene (C10 Cl8), octachloroacenaphthylene (C12 Cl8), decachloroanthracene (C14 Cl10), decachlorophenanthrene (C14 Cl10 ), decachloropyrene (C16 Cl10 ), decachlorofluoranthene (C16Cl10 ), C18 Cl10, C20Cl10, C22Cl12 and C24Cl12 were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.

Key words: Laser ablation, Synthesisl Perchlorinated polycyclic aromatic hydrocarbon

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