高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (6): 846.

• 研究简报 • 上一篇    下一篇

η2-C60[RhCl(CO)(PPh3)2]配合物的合成与表征

吴振奕, 程大典, 杨士, 林永生, 詹梦熊, 郑兰荪   

  1. 厦门大学化学系, 厦门 361005
  • 收稿日期:1998-09-14 出版日期:1999-06-24 发布日期:1999-06-24
  • 通讯作者: 詹梦熊
  • 作者简介:吴振奕,男,28岁,硕士,讲师
  • 基金资助:

    国家自然科学基金(批准号:29471024);教育部理科博士点基金

Synthesis and Characterization for Complex η2-C60[RhCl(CO)(PPh3)2]

WU Zhen-Yi, CHENG Da-Dian, YANG Shi-Yao, LIN Yong-Sheng, ZHAN Meng-Xiong, ZHENG Lan-Sun   

  1. Department of Chemstry, Xiamen University, Xiamen, 361005
  • Received:1998-09-14 Online:1999-06-24 Published:1999-06-24

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摘要： 从1985年Smaley等[1]发现C60等富勒烯至1996年富勒烯的发现者获诺贝尔化学奖期间,在化学、材料、物理等领域形成了富勒烯的研究热潮[2～5].现在科学工作者正以较大的注意力投向富勒烯的化学修饰,研究富勒烯各类衍生物的结构与性能之间内在联系.

关键词: C60[RhCl(CO)(PPh3)2], 合成, 表征

Abstract: The fullerene complex,η2-C60[RhCl(CO)(PPh3)2], has been prepared by the reaction of C60with RhCl(CO)(PPh3)2in benzene at room temperature. The new complex was characterized by elemental analysis, IR, XPS and electronic spectra. The result show that the complex of 2 form can be formed by C60bonding to RhCl(CO)(PPh3)2in the σ-π way. In addition, the complex structure has been supposed.

Key words: C60[RhCl(CO)(PPh3)2], Synthesis, Characterization

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