高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (10): 1594.

• 研究简报 • 上一篇    下一篇

杂多配合物[X(NbO2)W11O39]n-的合成与性质研究

杨启华, 戴慧聪, 刘景福   

  1. 东北师范大学化学系, 长春 130024
  • 收稿日期:1996-09-09 出版日期:1997-10-24 发布日期:1997-10-24
  • 通讯作者: 刘景福.
  • 作者简介:杨启华, 女, 27岁, 博士研究生.
  • 基金资助:

    国家自然科学基金

Synthesis and Properties of [X(NbO2)W11O39]n-

YANG Qi-Hua, DAI Hut-Cong, LIU Jing-Fu   

  1. Department of Chemistry, Northeast Normal University, Changchun 130024
  • Received:1996-09-09 Online:1997-10-24 Published:1997-10-24

关键词: 杂多配合物, Keggin结构, 合成

Abstract: Four new complexes MaHb[X (NbO2)W11O39]. nH2O (M=Me4N+, Bu4N+; X=Ga, Ge) were synthesized and characterized by elementary analysis, IR, UV-Vis,183W NMRand electrochemical method. 183W NMRspectra of the complexes consist of sixpeaks, as expected for monosubstituted Keggin-type.

Key words: Heteropolycomplexes, Keggin structure, Synthesis

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