高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (12): 1837.

• 论文 • 上一篇    下一篇

[Cu2(C6H5COO)4(C3H4N2S)2]的合成、晶体结

王冬梅1, 杨瑞娜1, 金斗满1, 罗保生2, 谌了容2   

  1. 1. 河南化学研究所, 郑州, 450003;
    2. 武汉大学分析测试中心
  • 收稿日期:1995-01-05 修回日期:1995-03-22 出版日期:1995-12-24 发布日期:1995-12-24
  • 通讯作者: 王冬梅,女,30岁,硕士.
  • 作者简介:王冬梅,女,30岁,硕士.
  • 基金资助:

    国家自然科学基金;配位化学重点实验室资助课题

Synthesis, Crystal Structure and Characterization of [Cu2(C6H5COO)4(C3H4N2S)2]

WANG Dong-Mei1, YANG Rui-Na1, JIN Dou-Man1, LUO Bao-Sheng2, CHEN Liao-Rong2   

  1. 1. Henan institute of Chemistry, Zhengzhou, 450003;
    2. Analysis and Measurement Center, Wuhan University, 430072
  • Received:1995-01-05 Revised:1995-03-22 Online:1995-12-24 Published:1995-12-24

摘要: 在2-氨基噻唑存在下,利用铜粉和过氧化苯甲酰的氧比加成反应,在丙酮中合成了双核铜(Ⅱ)配合物[Cu2(C6H5COO)4(C3H4N2S)2].晶体属单斜晶系,P21/n空间群,晶胞参数:a=1.0685(1)nm,b=1.9028(6)nm,c=1.7046(9)nm;α=γ=90°,β=96.49(3)°,V=3.443(4)nm3,Z=4.F(000)=824,Dc=1.5558g/cm3,μ=14.078cm-1,最终偏离因子R=0.04821,Rw=0.05314.通过元素分析、IR、TG、X射线粉末衍射表征了配合物的结构。

关键词: 铜, 配合物, 氧化加成, 晶体结构

Abstract: The metallic copper powder was oxidized by dibenzoyl peroxide in the presence of 2-aminothiazol in acetone resulting in the copper (Ⅱ) complex [Cu2 (C6H5COO)4(C3H4N2S)2].Crystal of the complex belongs to monoclinic, space group P21/n,with the crystal cell parameters:a = 1.0685 (1)nm, b=1. 9028(6)nm, c=1. 7046 (9) nm:α= γ=90°, β=96. 49(3)°, V= 3.443(4) nm3, Z=4,F(000)=824, Dc=1.5558g/cm3μ=14. 078cm-1, R=0.04821.Rw= 0. 05314.The complex was also characterized by elementary analy ses, IR, X-ray powder diffraction, and TG.

Key words: Copper complex, Oxidative addition, Crystal structure

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