高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (4): 481.

• 论文 • 上一篇    下一篇

ZSM-35分子筛的合成及模板效应的研究

宋天佑, 徐家宁, 佟瑶彩, 徐如人   

  1. 吉林大学化学系, 长春, 130023
  • 收稿日期:1993-04-23 修回日期:1993-12-01 出版日期:1994-04-24 发布日期:1994-04-24
  • 通讯作者: 宋天佑,男,45岁,博士,副教授.
  • 作者简介:宋天佑,男,45岁,博士,副教授.
  • 基金资助:

    国家自然科学基金

Studies on the Synthesis of ZSM-35 Molecular Sieve and Its Templating Effect

SONG Tian-You, XU Jia-Ning, TONG Yao-Cai, XU Ru-Ren   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1993-04-23 Revised:1993-12-01 Online:1994-04-24 Published:1994-04-24

摘要: 以1,6-己二胺为模板剂合成了ZSM-35分子筛,通过对比ZSM-35、ZSM-5和丝光沸石的合成条件,采用化学组成分析、热重分析及13CNMR等技术研究了1,6-己二胺和乙二胺的模板效应。结果表明,二者均对ZSM-35有较好的模板作用,而1,6-己二胺对ZMS-5的模板效应更佳。

关键词: ZMS-35分子筛, 合成, 模板效应, 13CNMR

Abstract: ZSM-35, ZSM-5 and mordenite are gained from the systems with 1,6-hexanediamine and ethylenediamine as templating agents, respectively.The templating effect during the formation of zeolite ZSM-35, ZSM-5 and mordenite were studied with the chemical analysis, thermal analysis and 13C NMR technique.The experimental results show that 1,6-hexanediamine and ethylenediamine have better templating effect for ZSM-35 molecular sieve than that for mordenite,and 1,6-hexanediamine is an excellent templating agent for ZSM-5 molecular sieve.

Key words: ZSM-35 molecular sieve, Synthesis, Templating effect, 13C NMR

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