高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (4): 445.

• 研究论文 •    下一篇

TiZSM-48型分子筛的快速合成及性能

张春雷, 吴志芸, 沙秀红, 徐翊华, 赵仲清   

  1. 吉林大学化学系, 长春 130023
  • 收稿日期:1992-06-20 修回日期:1992-09-10 出版日期:1993-04-24 发布日期:1993-04-24
  • 通讯作者: 张春雷
  • 基金资助:

    国家自然科学基金

Studies on the Rapid Synthesis, Structure and Properties for TiZSM-48

ZHANG Chun-Lei, WU Zhi-Yun, SHA Xiu-Hong, XU Yi-Hua, ZHAO Zhong-Qing   

  1. Department of Chemtstry, Jilin Unwersily, Changchan, 130023
  • Received:1992-06-20 Revised:1992-09-10 Online:1993-04-24 Published:1993-04-24

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被引次数

4

摘要： 在Na2O-1.6-C6H14N2-SiO2-TiO2-H2O体系中首次用快速动态法和静态法合成了TiZSM-48型分子筛,考察了两种合成方法的晶化动力学。利用XRD、IR、XPS、SEM、DRS、TG-DTA等测试手段对TiZSM-48型分子筛进行了表征,结果表明,Ti进入了分子筛骨架,动态法合成比静态法合成快得多,且样品的晶粒较小。热分析表明,两种方法合成的样品热稳定性均较好。

关键词: 快速合成, TiZSM-48, 性质, 骨架, 动态法

Abstract: The TiZSM-48 zeolite was synthesized under a dynamic condition by using1,6-hexamethy-lene-diamine as the template.The crystallizing rate of the dynamic state method was compared with that of the statical state method.The results show that the crystallizing rate of the former is much faster than that of the latter.The structure and properties of TiZSM-48 were investigated by IR, XRD, EPMA, XPS, DRS, ect..The results confirm that Ti4+ occupies Tsite of the framework of the zeolite and are well distributed.

Key words: Rapid synthesis, TiZSM-48, Properties, Framework, Dynamic state method

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