高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (10): 1402.

• 研究简报 • 上一篇    下一篇

S-两基O-苯基N-烷基硫赶磷酰胺酯的研究(Ⅴ)——丙硫基磷酰化合物的合成

杨小平1, 刘钊杰2   

  1. 1. 湘潭师范学院化学系, 湘潭 411100;
    2. 华中师范大学有机合成研究所
  • 收稿日期:1993-01-04 修回日期:1993-04-09 出版日期:1993-10-24 发布日期:1993-10-24
  • 通讯作者: 杨小平, 29岁, 男, 硕士, 讲师.
  • 作者简介:杨小平, 29岁, 男, 硕士, 讲师.
  • 基金资助:

    国家自然科学基金

Synthesis of S-Propyl O-Phenyl N-AlkyI Thiolophosphoranlides

YANG Xiao-Ping1, LIU Zhao-Jie2   

  1. 1. Department of Chemistry, Xiangtan Normal University, Xiangtan, 411100;
    2. Institute of Organic Synthesis, Central China Normal University, Wuhan, 430070
  • Received:1993-01-04 Revised:1993-04-09 Online:1993-10-24 Published:1993-10-24

PDF (PC)

关键词: S-丙基, 硫赶磷酰胺酯, 合成, 双溶剂法

Abstract: Nine new S-propyl 0-phenyl N-alkyl thiolophosphoramides were synthesized by direct aminolysis of S-propyl O-phenyl thiolophosphorochlorate, which were prepared by reaction of S-propyl thiolophosphorodichlorate with phenol, without separation.The first attempt using inorganic baseCsodium hydroxide) as acid-acceptor, benzene-water as double solvent to synthesize the target products was successful.But the method can not obtain the aminolysis products by secondary amines.The reason was discussed.

Key words: S-Propyl, Thiolophosphoramides, Synthesis, Double solvent method

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