高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (11): 1398.

• 论文 • 上一篇    下一篇

金属有机自由基离子盐[Fe(CpMe)2][M(dmit)2]和[FeCp(Tol)]n[M(dmit)2]的合成和固体导电性质

秦金贵, 周伟华, 丁永平, 刘道玉   

  1. 武汉大学化学系, 武汉, 430072
  • 收稿日期:1991-12-28 修回日期:1991-08-17 出版日期:1992-11-24 发布日期:1992-11-24
  • 通讯作者: 刘道玉
  • 基金资助:

    国家自然科学基金

Synthesis and Conductivity of Organometallic Solids [Fe(CpMe)2][M(dmit)2] and [FeCp(Tol)]n[M(dmit)2]

QIN Jin-Gui, ZHOU Wei-Hua, DING Yong-Pmg, LIU Dao-Yu   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1991-12-28 Revised:1991-08-17 Online:1992-11-24 Published:1992-11-24

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摘要： 报道了6个新的含均同或混合茂铁阳离子和[M(dmit)2]阴离子的金属有机自由基离子盐类化合物[Fe(CpMe)2]IM(dmit)2]和[FeCp(Tol)],[M(dmit)2]的合成和鉴定,测定了化合物的电导率,讨论了化合物的结构对电导率的影响,发现[Fe(CpMe)2][M(dmit)2]的室温电导率比相应的[M(mnt)2]阴离子盐要高37个数量级.

关键词: 金属有机化合物, 自由基离子盐, dmit, 合成, 电导性

Abstract: Six new organometallic radical ionic salts,[Fe(CpMe)2][M(dmit)2] and [FeCp(Tol)]n[M(dmit)2]n(M=Ni,Pd,Pt,Cu or Co;CpMe=methylcyclopentadienyl;Tol=toluene;H2dmit=4,5-dimercapto-1,3-dithiole-2-thione;n=1 or 2)were synthesized,and characterized by elemental analysis,infrared and mass spectroscopy.The electrical conductivity of solid state was reported and discussed in terms of structure-property relationship.

Key words: Organometailic compounds, Radical ionic salts, Dmit, Synthesis, Conductivity

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