高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (6): 711.

• 论文 •    下一篇

K10P2Mo17O61·16H2O的合成及性质研究

王恩波, 由万胜, 刘景福, 胡长文   

  1. 东北师范大学化学系, 130024
  • 收稿日期:1989-09-05 出版日期:1991-06-24 发布日期:1991-06-24
  • 通讯作者: 王恩波
  • 基金资助:

    国家自然科学基金

Synthesis and Characterization of Potassium 2:17 Molybdophosphate

Wang En-bo, You Wan-sheng, Liu Jing-fu, Hu Chang-wen   

  1. Department of Chemistry, Northeast Normal Vniversity, Changchun, 130024
  • Received:1989-09-05 Online:1991-06-24 Published:1991-06-24

摘要: 本文报道了标题杂多配合物的合成方法及其IR、UV、氧化还原及热稳定性,推测其结构为α2-型,发现空穴的形成使其氧化还原反应变得不可逆。

关键词: 钼磷酸钾, 杂多配合物, 合成

Abstract: The K10P2Mo17O61·16H2O was synthesized by the improved method. The IR, UV and oxidation-reduction were discussed. It is inferred that the structure of the compounds is a2-isomer. The hole makes the oxidation-reduction irreversible. The thermal stabillity and X-ray powder diffraction of the compounds were also studied.

Key words: Potassium molybdophosphate, Heteropoly complex, Synthesis

TrendMD: