高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (7): 759.

• 研究简报 • 上一篇    下一篇

α,β-不饱和醇的选择性氧化反应研究——两种新型聚合物载体氧化剂的合成及选择性

杨辉荣1, 黎碧娜1, 陆乾生2   

  1. 1. 广东工学院化工系;
    2. 华南师范大学化学系
  • 收稿日期:1989-01-08 出版日期:1990-07-24 发布日期:1990-07-24
  • 通讯作者: 杨辉荣

Studies on Selective Oxidation of α,β-Unsaturated Alcohols——The Synthesis of Two New Types of Polymer Supported Oxidizing Reagents and Their Excellent Selectivity

Yang Hulrong1, Li Bina1, Lu Qiansheng2   

  1. 1. Department of Chemical Engineering, Guangdong Institute of Technology, Guangzhou;
    2. Department of Chemistry, South China Normal University, Guangzhou
  • Received:1989-01-08 Online:1990-07-24 Published:1990-07-24

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摘要： 近年来,应用聚合物载体氧化剂进行醇类氧化反应的研究已有报道[1～5],蔡坤等人[6]采用盐酸三甲胺为配体的三氧化铬,制成对醇类具有高度氧化选择性的氧化剂。

关键词: 聚合物载体氧化剂, &alpha, &beta, -不饱和醇, 选择性氧化, 合成

Abstract: Two new types of polymer supported oxidizing reagents——dichromic acid type tertiaryamine resin and dichromic acid type quaternary ammonium resin were synthesized by using jel tertiary amine resin and jel quaternary ammonium resin as the supports. These two new types of polymer supported oxidizing reagents can successfully oxidate the α, β-unsaturated alcohols into the corresponding α,β-unsaturated aldehydes, but can not oxidate the saturated alcohols under the similar condition, which exhibits excellent selectivity.

Key words: Polymer supported oxidizing reagent, α,β-Unsaturated alcohols, Selective oxidation, Synthesis

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