高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (6): 565.

• 研究论文 • 上一篇    下一篇

稀土冠醚配合物的研究(ⅩⅦ)——稀土硝酸盐Schiff碱型大环配合物的合成和性质

雷秀斌, 季振平, 萧文锦   

  1. 武汉大学化学系
  • 收稿日期:1988-10-05 出版日期:1990-06-24 发布日期:1990-06-24
  • 通讯作者: 萧文锦
  • 基金资助:

    国家自然科学基金

Studies on Rare Earth Coordination Compounds with Crown Ether (ⅩⅦ) )——Syntheses and Properties of Rare Earth Coordination Compounds of Schiff Base Macrocyclic Ligand

Lei Xiubin, Ji Zhenping, Xiao Wenjin   

  1. Department of Chemistry, Wuhan University, Wuhan
  • Received:1988-10-05 Online:1990-06-24 Published:1990-06-24

摘要: 采用模板反应合成了Schiff碱型大环L的15种稀土金属离子的配合物。对配合物的组成进行了推测和紫外光谱、红外光谱、摩尔电导以及差热-热重等项分析。

关键词: 稀土配合物, Schiff碱大环配体, 合成, 性质

Abstract: Fifteen lanthanoid complexes of Schiff base Lmacrocyclic ligand were prepared by template reactions. Their compositions and structures were characterized by elemental analysis, IR, UV spectra and electrical conductance measurement. The stability of complexes was studied by DTA-TG analyses, and L macrocyclic ligand was synthesized in order to compare it with the complexes.

Key words: Rare earth complex, Schiff base macrocyclic ligand, Synthesis, Property

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