高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (11): 1077.

• 研究论文 • 上一篇    下一篇

二乙胺基尾式卟啉钴的合成及其载氧性质

曹锡章, 王清民, 师同顺   

  1. 吉林大学化学系
  • 收稿日期:1988-04-23 出版日期:1989-11-24 发布日期:1989-11-24
  • 通讯作者: 王清民
  • 基金资助:

    国家自然科学基金

Studies on Preparation and Carrying Oxygen of A New Tailed Porphyrincobalt(Ⅱ)

Cao Xizhang, Wang Qingmin, Shi Tongsun   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1988-04-23 Online:1989-11-24 Published:1989-11-24

PDF (PC)

被引次数

2

摘要： 合成了1种新的尾式卟啉钴——间-[邻-(4-二乙胺基丁酰胺基)苯基]三苯基卟啉合钴(Ⅱ)配合物,测定了电子光谱、红外光谱、质谱、电子自旋波谱,研究了这种尾式卟啉钴与有机碱和双原子小分子CO、NO的轴向反应及其可逆载氧性质.

关键词: 间-[邻-(4-二乙胺基丁酰胺基)苯基]三苯基卟啉合钴(Ⅲ), 合成, 载氧

Abstract: Anew tailed porphyrincobalt complex, meso-mono-[o-(4-diethylamino) butyramidophenyl] triphenal porphyrin cobalt (Ⅱ), meso-MDBPTPP Co(Ⅱ), was prepared and the formation of it was monitored by electronic spectrum.IRspectrum exhibits vCo-Nband at 310cm-1, and 1001 cm-1 peak attributable to the porphyrin ring' s vibration.EPRspectrum and Ⅱeff demonstrate that the central ion is cobaltous.Mass spectrum demonstrates that the molecular weight of meso-MDBPTPP Co(Ⅱ) is 828.The results of axial reactions demonstrate that meso-MDBPTPP Co(Ⅱ) complex has as ability reyer sibly to carry O2 at low temperature.

Key words: meso-MDBPTPPCo(Ⅱ), Preparation, Carrying oxygen

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