MOFs基材料在光催化CO2还原中的应用

doi:10.7503/cjcu20180688

摘要/Abstract

摘要：

系统总结了金属有机框架(MOFs)基材料在光催化还原CO₂中的最新研究进展, 其中包括MOFs直接作为光催化剂和作为复合光催化2个主要部分, 讨论了MOFs基光催化剂在催化还原CO₂方面展现出的独特优势, 并对MOFs基光催化剂的结构稳定性与CO₂转化效率等问题进行讨论与分析, 对未来发展趋势进行了展望.

关键词: 金属有机框架材料, 二氧化碳, 光催化还原, 光催化剂, 复合材料

Abstract:

We summarize the recent progress of metal-organic frameworks(MOFs) used for photocatalytic CO₂ reduction, including MOFs employed directly as the photocatalysts for CO₂ reduction and as components in hybrid photocatalytic systems for CO₂ reduction. Meanwhile, the fascinating features of MOFs-based photocatalysts in CO₂ reduction are presented. Finally, the challenges and perspectives regarding of MOFs-based photocatalyst are also discussed.

Key words: Metal-organic frameworks(MOFs)-based material, CO₂, Photocatalytic reduction, Photocatalyst, Compound material

中图分类号:

O644
TQ152

TrendMD:

何鹏琛, 周健, 周阿武, 豆义波, 李建荣. MOFs基材料在光催化CO₂还原中的应用. 高等学校化学学报, 2019, 40(5): 855.

HE Pengchen,ZHOU Jian,ZHOU Awu,DOU Yibo,LI Jianrong. MOFs-Based Materials for Photocatalytic CO₂ Reduction^†. Chem. J. Chinese Universities, 2019, 40(5): 855.

图/表 7

Fig.1 Structure(A) and CO2 and N2 adsorption isotherms(B) of PCN-222, UV-Vis spectra of PCN-22 and H2TCPP(C) and the amount of HCOO-(D) with PCN-22 as catalyst[33] (D) a. PCN-222; b H2TCPP; c. no PCN-222; d. no TEOA; e. no CO2. Copyright 2015, American Chemical Society.

Fig.6 HKUST-1 and HKUST-1/TiO2 formation steps inside a microdroplet(A), TEM images of as-synthesized HKUST-1(B) and 33.3 HKUST-1/TiO2(C) at 300 ℃ and CO2 photoreduction performance of TiO2 and HKUST-1/TiO2 composites(D)[52] Inset of (B): the image of the contact angle measurement of HKUST-1 surface. Copyright 2017, American Chemical Society.

Fig.7 Schematic illustration of the fabrication process and CO2 photoreduction process of CsPbBr3/ZIFs(A) and photocatalytic CO2 reduction performances of CsPbBr3 and CsPbBr3@ZIFs(B, C)[59] Copyright 2018, American Chemical Society.

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MOFs基材料在光催化CO₂还原中的应用

MOFs-Based Materials for Photocatalytic CO₂ Reduction^†

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