Synthesis and Crystal Structure of a Chainlike Coordination Polymer [Cu(en)2]2[Cu(en)2α-AsⅢ8VⅣ14O42(HPO4)]·8H2O</

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Synthesis and Crystal Structure of a Chainlike Coordination Polymer [Cu(en)₂]₂[Cu(en)₂α-As^Ⅲ₈V^Ⅳ₁₄O₄₂(HPO₄)]·8H₂O
LI Ya-Feng, ZHANG Li-Mei, LIU Chun-Lei, ZHANG Fan, ZOU Jin, SUN Jin-Xu, BAI Yuan, SUN Yan-Qun, TIAN Yong

College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China

`Received:`2005-11-17 `Revised:`1900-01-01 `Online:`2006-12-10 `Published:`2006-12-10

`Contact:` LI Ya-Feng

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Abstract: A novel coordination polymer, [Cu(en)₂]₂[Cu(en)₂α-As^Ⅲ₈V^Ⅳ₁₄O₄₂(HPO₄)]·8H₂O, was hydrothermally synthesized and structurally determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system, space group P2(1)/c, a=1.501 0(2) nm, b=1.860 9(3) nm, c=2.646 7(4) nm, β=102.169(5)°, V=7.227(2) nm³, Z=4, D_c=2.551 Mg/m³, F(000)=5 364. The structural refinement indicated that the tilted compound was a chainlike coordination polymer based on cluster [α-As₈V₁₄O₄₂·(HPO₄)]^6- as the building blocks. Two of the three Cu(en)₂ groups acted as the balance cation and the other one connected the anion cage [α-As₈V₁₄O₄₂(HPO₄)]^6- to form the 1D chain.

CLC Number:

O614

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LI Ya-Feng, ZHANG Li-Mei, LIU Chun-Lei, ZHANG Fan, ZOU Jin, SUN Jin-Xu, BAI Yuan, SUN Yan-Qun, TIAN Yong. Synthesis and Crystal Structure of a Chainlike Coordination Polymer [Cu(en)₂]₂[Cu(en)₂α-As^Ⅲ₈V^Ⅳ₁₄O₄₂(HPO₄)]·8H₂Odoi: .

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