Electrochemical Behaviour of Cyanoethenyl Aniline Derivatives

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1420.

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Electrochemical Behaviour of Cyanoethenyl Aniline Derivatives

ZHANG Dong¹, JIANG Yue-Shun¹, WANG De-Jun¹, YANG Sai-Peng¹, LI Tie-Jin¹, ZHANG Bao-Wen²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Institute of Photographic Chemistry, Academia Sinica, Beijing

Received:1991-11-26 Revised:1992-08-15 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: The electrochemical behaviour of the electron donor-acceptor model compounds,cya-noethenyl aniline derivatives was investigated by cyclic voltammetry.The effects of donating electron group-NH₂,-N(CH₃)₂ and withdrawing electron group cyanothenyl group on electrochemical behaviour of these compounds were studied in detail.The structures of electroox-idation and electroreduction state of these compounds were proposed,and the mechanism of the electrode reaction was studied by comparing the effects of tert-radical,sec-radical and pri-radical on electrochemical behaviour of these compounds.

Key words: Cyanoethenyl aniline, Electron donor-acceptor, Cyclic voltammetry

TrendMD:

ZHANG Dong, JIANG Yue-Shun, WANG De-Jun, YANG Sai-Peng, LI Tie-Jin, ZHANG Bao-Wen. Electrochemical Behaviour of Cyanoethenyl Aniline Derivatives[J]. Chem. J. Chinese Universities, 1992, 13(11): 1420.

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Electrochemical Behaviour of Cyanoethenyl Aniline Derivatives

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