Self-assembly of Phthalocyanine-carbon Nanotubes Dispersed in Micelle and Light Induced Long-lived Charge Separation State

doi:10.3969/j.issn.0251-0790.2012.04.028

Abstract

Abstract: To mimic the primary process in photosynthesis, tetrasulfonated zinc phthalocyanine(ZnPcS₄) and single-walled carbon nanotubes(SWCNT) were assembled to noncovalent electron donor-acceptor(D-A) complex assisted by sodium dodecyl sulfate(SDS) micelle, which disaggregate both SWCNTs and phthalocyanines in aqueous solution. The D-A complex is featured by the new absorption at 707 nm and completely non fluorescence, due to the efficient intra-molecular photo induced electron transfer revealed by both steady state and time resolved fluorescence spectra. The charge separation state(CSS) was observed by laser flash photolysis and showed a long lifetime of 42 μs observable by kinetic analysis. The long-lived CSS is due to the triplet electron transfer which is made possible by the low oxidation potential of the phthalocyanine(good donor) and the low reduction potential of SWCNT(good acceptor). The result shows that SWCNT may be applied in artificial photosynthesis.

Key words: Photoinduced electron transfer, Charge separation state, Electron donor-acceptor, Sulfonated zinc phthalocyanine, Single-walled carbon nanotube(SWCNT)

CLC Number:

O644.12

TrendMD:

SHAO Xiao-Na, ZHANG Xian-Fu. Self-assembly of Phthalocyanine-carbon Nanotubes Dispersed in Micelle and Light Induced Long-lived Charge Separation State[J]. Chem. J. Chinese Universities, 2012, 33(04): 806.

References

[1] Coropceanu V., Malagoli M., Andre J. M., Bredas J. L.. J. Am. Chem. Soc.[J], 2002, 124: 10519—10530 [2] LI Xu-Bing(李旭兵), WANG Xiao-Jun(王晓军), WANG Ge-Xia(王格侠), XING Ling-Bao(邢令宝), ZHANG Li-Ping(张丽萍), TONG Zhen-He(佟振合), WU Li-Zhu(吴骊珠). Imag. Sci. Photochem.(影像科学与光化学)[J], 2010, 28(4): 241—247 [3] ZHAO Hai-Ying(赵海英), CHEN Chen(陈晨), ZHU Yi-Zhou(朱义州), ZHENG Jian-Yu(郑健禺). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(5): 933—937 [4] Haldi A., Kimyonok A., Domercq B., Hayden L. E., Jones S. C., Marder S. R., Weck M., Kippelen B.. Adv. Funct. Mater.[J], 2008, 18: 3056—3062 [5] Osakada Y., Kawai K., Fujitsuka M., Majima T.. Nucleic Acids Res.[J], 2008, 36(17): 5562—5570 [6] Osakada Y., Kawai K., Fujitsuka M., Majima T.. Chem. Commun.[J], 2008: 2656—2658 [7] JIN Ying-Xue(金英学), TAN Guang-Hui(谭广慧), WANG Tian-Chi(王天赤), WEI Shu-Quan(魏树权), WANG Jin-Jun(王进军). Chin. J. Org. Chem. (有机化学)[J], 2010, 30(4): 595—600 [8] CHEN Nian-You(陈年友), ZHAO Sheng-Fang(赵胜芳), DONG Jia-Qing(董甲庆), TIAN You-Ping(田又平), LI Zao-Ying(李早英). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(7): 1466—1471 [9] Wrobel D., Graja A.. Coord. Chem. Rev.[J], 2011, 255(21/22): 2555—2557 [10] Kalyanasundaram K., Graetzel M.. Curr. Opin. Biotechnol.[J], 2010, 21(3): 298—310 [11] ZHANG Hai-Ping(张海平), ZHOU Ya-Lin(周亚琳), ZHANG Man-Hua(张曼华), SHEN Tao(沈涛), LI Yu-Liang(李玉良), ZHU Dao-Ben(朱道本). Acta Chim. Sinica(化学学报)[J], 2002, 60(9): 1581—1585 [12] Liu J. Y, EI-Khouly M. E., Fukuzumi S., Ng D. K. P.. Chem. Eur. J.[J], 2011, 17(5): 1605—1613 [13] D’ Souza F., Ito O.. Chem. Commun.[J], 2009: 4913—4928 [14] Zhang X. F., Cui X., Liu Q., Zhang F.. Phys. Chem. Chem. Phys.[J], 2009, 11(18): 3566—3572 [15] Zhang X. F., Cui X., Liu Q., Zhang F.. Chem. Phys. Chem.[J], 2008, 9(11): 1514—1518 [16] Iijima S.. Nature[J], 1991, 354(6348): 56—58 [17] Wildoer J. W. G., Venema L. C., Rinzier A. G., Smalley R. E., Dekker C.. Nature[J], 1998, 391(6662): 59—62 [18] Odom T. W., Huang J., Kim P., Lieber C. M.. J. Phys. Chem. B[J], 2000, 104(13): 2794—2809 [19] LI Ming(李明), WAN Chao-Ying(万超瑛), ZHANG Yong(张勇). Polym. Bull.(高分子通报)[J], 2009, 9(10): 1—8 [20] LIAN Yong-Fu(廉永福), WU Xiu-Li(吴秀力). J. Eng. Heilongjiang University(黑龙江大学工程学报)[J], 2010, 1(1): 58—62 [21] Zhang X. F., Wang Y., Niu L. H.. J. Photochem. Photobiol. A: Chemistry[J], 2010, 209: 232—237 [22] Zhang X. F., Xi Q., Zhao J.. J. Mater. Chem.[J], 2010, 20(5): 6726—6733 [23] LI Xi-You(李希友), CHEN Yan-Li(陈艳丽), XU Hui-Jun(许慧君). Acta Physico-Chimica Sinica(物理化学学报)[J], 1999, 15(6): 512—517 [24] WANG Shuang-Qing(王双青), GAN Quan(甘泉), SHEN Shu-Yin(沈淑引), XU Hui-Jun(许慧君), YANG Guo-Qiang(杨国强). Acta Chim. Sinica(化学学报)[J], 2004, 62(22): 2209—2212 [25] WANG Shuo(王硕), YU Jia-Yi(于佳一), LI Wei(李惟), LI Fei(李菲). Chem. J. Chinese Universities(高等学校化学学报)[J], 2011, 32(4): 915—919 [26] Zhang X., Ma J., Huo X., Yan F., Xu H.. Prog. Nat. Sci.[J], 1992, 2(6): 550—555 [27] YUAN Jie(袁婕), LIU Bao-Chun(刘宝春), YANG Zhi-Wei(杨志伟). Chem. Ind. Times(化工时刊)[J], 2007, 21(10): 55—59 [28] Jimenez L. L., Henrio P. Y., Lund A., Laurie T. M., Garcia S. A. P., Nyborg L., Hassander H., Bertilsson H., Rychwalski R. W.. Compos. Sci. Technol.[J], 2007, 67: 844—854 [29] CAO Shu-Qing(曹淑青), LIU Wei(刘巍). J. Yangzhou University(扬州大学学报)[J], 2008, 11(1): 29—33 [30] LV Lin(吕琳), WU Xing(吴星), YUAN Shi-Hai(袁诗海). Spectro. Spec. Anal.(光谱学与光谱分析)[J], 1999, 19(5): 751—754 [31] Clack D. W., Hush N. S., Woolsey I. S.. Inorg. Chim. Acta[J], 1976, 19: 129—132 [32] Kavan L., Rapta P., Dunsch L.. Chem. Phys. Lett.[J], 2000, 328: 363—368 [33] Carmichael I., Hug G. L.. J. Phys. Chem. Ref. Data[J], 1986, 15: 1—250 [34] Zhang X. F., Zheng H. W., Jin S. M., Wang R. Y.. Dyes Pigm.[J], 2010, 87(2): 139—143 [35] Ishii K., Kobayashi N., Eds: Kadish K. M., Smith K. M., Guilard R.. The Porphyrin Handbook[M], San Diego: Academic Press, 2003: 1—42 [36] Mark J., Stillman M. J.. Porphyrins Phthalocyanines[J], 2001, 5: 67—76 [37] Guldi D. M., Marcaccio M., Paolucci D., Paolucci F., Tagmatarchis N., Tasis D., Vazquez E., Prato M.. Angew. Chem. Int. Ed.[J], 2003, 42: 4206—4209 [38] Guldi D. M., Marcaccio M., Paolucci F., Tagmatarchis N., Tasis D., Vazquez E., Prato M.. Angew. Chem.[J], 2003, 115: 4338—4341 [39] Zhang X. F., Xi Q.. Carbon[J], 2011, 49: 3842—3850