Studies on the Electrocatalytic Reduction of Carbon Dioxide (Ⅲ)——The Electrocatalytic Activities of Metalloporphyrin of TPP, TMAP, TMAPT Series

Abstract

Abstract: The Catalytic actions of five water-nonsoluble coordination compounds of metal-tetraphenylporphyrin MTPP(M = Mn,Fe,Co, Ni) and cobalt tetra (dime-thylaniline) porphyrin CoTMAP and four water-soluble coordination compounds of tetrakis (4-trimethylaniline) porphyrin iodide MTMAPI(M = Mn, Fe, Pd and Rh) for the electroreduction of CO₂ has been studied. The result is as follows: at 1.4Vmaximum current efficiencies were obtained for CoTPP CoTMAP and FeTMAPI. Their values(%) are 64 for CoTPP. 76 CoTMAP and 98 FeTMAPI

Key words: Carbon dioxide, Electrocatalytic reduction, Metalloporphyrin

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Cao Xizhang, Zheng Guodong, Teng Yongfu . Studies on the Electrocatalytic Reduction of Carbon Dioxide (Ⅲ)——The Electrocatalytic Activities of Metalloporphyrin of TPP, TMAP, TMAPT Series[J]. Chem. J. Chinese Universities, 1988, 9(8): 861.

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Studies on the Electrocatalytic Reduction of Carbon Dioxide (Ⅲ)——The Electrocatalytic Activities of Metalloporphyrin of TPP, TMAP, TMAPT Series

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