Chem. J. Chinese Universities ›› 2022, Vol. 43 ›› Issue (7): 20220222.doi: 10.7503/cjcu20220222

• Review • Previous Articles     Next Articles

Recent Advances on Indirect Conversion of Carbon Dioxide to Chemicals

HUANG Xiaoshun, MA Haiying, LIU Shujuan, WANG Bin, WANG Hongli, QIAN Bo, CUI Xinjiang(), SHI Feng()   

  1. Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China
  • Received:2022-04-09 Online:2022-07-10 Published:2022-05-10
  • Contact: CUI Xinjiang,SHI Feng E-mail:xinjiangcui@licp.cas.cn;fshi@licp.cas.cn
  • Supported by:
    the National Natural Science Foundation of China(21955207);the Natural Science Foundation of Gansu Province, China(21JR7RA096);the Major Project of Gansu Province, China(21ZD4WA021)

Abstract:

Due to the difficulty of direct carbon dioxide utilization, the indirect conversion of carbon dioxide into its derivatives such as cyclic carbonate plays one of the most important methods to realize the transformation of carbon dioxide, which has a promising application prospect. In this review, we outline recent advances in the indirect conversion of carbon dioxide to valued added chemicals via cyclic carbonate as relay molecular, focusing on the homogeneous and heterogeneous catalytic systems in the hydrogenation, alcoholysis and ammonolysis of cyclic carbonate and also investigating the reaction mechanism. Finally, we provide the challenges and opportunities in this area.

Key words: Carbon dioxide, Cyclic carbonate, Hydrogenation, Alcoholysis, Ammonolysis

CLC Number: 

TrendMD: