Synthesis of Self-assembled α-Fe2O3/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties

doi:10.7503/cjcu20200153

Abstract

Abstract: Self-assembed α-Fe₂O₃/reduced graphene oxide hydrogel(3DGH) composites were synthsized by facile hydrothermal method. The samples were characterized by X-ray diffraction(XRD), Raman spectroscopy(Raman), X-ray photoelectron spectroscopy(XPS), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The α-Fe₂O₃ nanoparticles(about 100 nm in diameter) grow on the three-dimensional porous structure of reduced graphene oxide(RGO). In addition, the particle size of α-Fe₂O₃ can be controlled from 200 nm to 30 nm via adjusting the loading of Fe³⁺. This results show that the α-Fe₂O₃/3DGH composite with a Fe³⁺ loading amount of 40% and particle size of 100 nm has the maximum specific capacitance(750.8 F/g at 1 A/g) and good cyclic performance(the specific capacitance retention is 81.9% after 5000 cycles at 10 A/g), which is higher than that of pure α-Fe₂O₃(251. F/g at 1 A/g and 43.8% after 5000 cycles).

Key words: α-Fe₂O₃, Graphene oxide, Porous framework, Supercapacitor

CLC Number:

O646

TrendMD:

ZHANG Weiguo, FAN Songhua, WANG Hongzhi, YAO Suwei. Synthesis of Self-assembled α-Fe₂O₃/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties[J]. Chem. J. Chinese Universities, 2020, 41(8): 1850.

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Synthesis of Self-assembled α-Fe₂O₃/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties

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