Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW12O40｝ Hybrid

doi:10.7503/cjcu20210556

Abstract

Abstract:

H₄SiW₁₂O₄₀ was used as a precursor to synthesize biimidazole-modified supramolecular hybrid under hydrothermal condition， and its chemical formula was determined to be ［Co（bim）₂（H₂O）₂］［H₂SiW₁₂O₄₀］·2H₂O（1）（bim=biimidazole） by elemental composition and thermal gravity（TG） analysis. Single-crystal diffraction analysis shows that， the compound is composed of ［H₂SiW₁₂O₄₀］^2?，［Co（bim）₂（H₂O）₂］²⁺ and two H₂O. At the same time， the components form 1D to 3D structures through hydrogen bond and supramolecular interaction. Using glassy carbon， carbon cloth and nickel foam as the current collectors， when the current density is 1 A/g， in the three-electrode system， compound 1 shows the specific capacitance（350.09， 107.02 and 186.83 F/g）， better than most literature reports， and with capacitance retention of 94.5%， 92.8% and 95.1% after 5000 cycles. The kinetic analysis shows that the charge storage mechanism of the compound is dominated by surface-controlled electric charges. And simulataneously in the foamed nickel two-electrode system， the compound shows the specific capacitance 80.00 F/g at 1 A/g current density， an energy density of 9.41 W·h/kg for a power density of 130.83 W/kg in a voltage window of 0.75 V， and an outstanding cycle stability with 92.4% capacitance retention after 5000 cycles. It is shown that the synthetic hybrid is a better candidate material for supercapacitor electrodes.

Key words: Polyoxometalate, ［SiW₁₂O₄₀］^4?, Hydrothermal synthesis, Supercapacitor performance

CLC Number:

O614

TrendMD:

LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid[J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.

Figures/Tables 7

Fig.1 IR spectra of crystal and 1?GCE after cycles(A) and XRD patterns of compound 1(B)

Fig.2 SEM image(A), EDS spectrum(B), corresponding elemental mapping of C(C), Co(D), N(E), O(F), Si(G) and W(H) of compound 1

Fig.3 2D(A) and 3D structures(B) of compound 1

Fig.4 CV curves(A), the relationship between lgi and lgv(B), relationship between v-1/2 and total charge(C), normalized contribution ratio of the surface?controlled electric charges(Qc) and diffusion?controlled(Qd) charge storage capacities at lower scan rates(D) of compound 1

Fig.5 GCD curves(A) of 1?GCE, cycling stability(B) and electrochemical impedance spectroscopy(EIS) curves(C) before and after cycles of three electrodes

Fig.6 CV(A) and GCD(B) curves of three electrodes in 1 mol/L Na2SO4

Fig.7 CV curves(A), GCD curves(B), cycling stability(C) and EIS curves of before and after cycles(D) for symmetric button battery

References 33

1	Bae J.， Song M. K.， Park Y. J.， Kim J. M.， Liu M. L.， Wang Z. L.， Angew. Chem.， Int. Ed.， 2011， 50（7）， 1683—1687
2	Rakhi R. B.， Chen W.， Cha D.， Alshareef H. N.， Nano Lett.， 2012， 12（5）， 2559—2567
3	Lu X. H.， Wang G. M.， Zhai T.， Yu M. H.， Gan J. Y.， Tong Y. X.， Li Y.， Nano Lett.， 2012， 12（3）， 1690—1696
4	Li Z. P.， Wang J. Q.， Niu L.Y.， Sun J. F.， Gong P. W.， Hong W.， Ma L. M.， Yang S. R.， J. Power Sources， 2014， 245， 224—231
5	Yu D. S.， Qian Q. H.， Wei L.， Jiang W. C.， Goh K. L.， Wei J.， Zhang J.， Chen Y.， Chem. Soc. Rev.， 2015， 44， 647—662
6	Wang H.， Hamanaka S.， Nishimoto Y.， Irle S.， Yokoyama T.， Yoshikawa H.， Awaga K.， J. Am. Chem. Soc.， 2012， 134， 4918—4924
7	Yamada A.， Goodenough J. B.， J. Electrochem. Soc.， 1998， 145（3）， 737—743
8	Ji Y. C.， Huang L. J.， Hu J.， Streb C.， Song Y. F.， Energy Environ. Sci.， 2015， 8， 776—789
9	Genovese M.， Lian K.， Current Opinion Solid State Mater. Sci.， 2015，19， 126—137
10	Wang G. N.， Chen T. T.， Li S. B.， Pang H. J.， Ma H. Y.， Dalton Trans.， 2017， 46， 13897—13902
11	Wang G. N.， Chen T. T.， Wang X. M.， Ma H. Y.， Pang H. J.， Eur. J. Inorg. Chem.， 2017， 5350—5355
12	Chai D. F.， Hou Y.， O’Halloran K. P.， Pang H. J.， Ma H. Y.， Wang G. N.， Wang X. M.， ChemElectroChem， 2018， 5（22）， 3443—3450
13	Chai D. F.， Gómez⁃García C. J.， Li B.， Pang H. J.， Ma H. Y.， Wang X. M.， Tan L. C.， Chem. Eng. J.， 2019， 373， 587—597
14	Chai D. F.， Xin J. J.， Li B.， Pang H. J.， Ma H. Y.， Li K. Q.， Xiao B. X.， Wang X. M.， Tan L. C.， Dalton Trans.， 2019， 48， 13026—13033
15	Wang G. N.， Chen T. T.， Gómez⁃García C. J.， Zhang F.， Zhang M. Y.， Ma H. Y.， Pang H. J.， Wang X. M.， Tan L. C.， Small， 2020， 16， 2001626
16	Roy S.， Vemuri V.， Maiti S.， Manoj K. S.， Subbarao U.， Peter S. C.， Inorg. Chem.， 2018， 57， 12078—12092
17	Wang K. B.， Wang Z. K.， Wang S.， Chu Y.， Xia R.， Zhang X. Y.， Wu H.， Chem. Eng. J.， 2019， 367， 239—248
18	Ma X. Y.， Yu K.， Yuan J.， Cui L. P.， Lv J. H.， Dai W. T.， Zhou B. B.， Inorg. Chem.， 2020， 59， 5149—5160
19	Gong L. G.， Qi X. X.， Yu K.， Gao J. Q.， Zhou B. B.， Yang G. Y.， J. Mater. Chem. A， 2020， 8， 5709—5720
20	Cui L. P.， Yu K.， Lv J. H.， Guo C. H.， Zhou B. B.， J. Mater. Chem. A， 2020， 8， 22918—22928
21	Du N. N.， Gong L. G.， Fan L. Y.， Yu K.， Luo H.， Pang S. J.， Gao J. Q.， Zheng Z. W.， Lv J. H.， Zhou B. B.， ACS Appl. Nano Mater.， 2019， 2， 3039—3049
22	Wang K. P.， Yu K.， Lv J. H.， Zhang M. L.， Meng F. X.， Zhou B. B.， Inorg. Chem.， 2019， 58， 7947—7957
23	Gao J. Q.， Gong L. G.， Fan L. Y.， Yu K.， Zheng Z. W.， Zhou B. B.， ACS Appl. Nano Mater.， 2020， 3， 1497—1507
24	Zhong R.， Cui L. P.， Yu K.， Lv J. H.， Guo Y. H.， Zhou B. B.， Inorg. Chem.， 2021， 60， 9869—9879
25	North E. O.， Inorg. Synth.， 1939， 1， 129
26	Rocchiccioli⁃Deltcheff C.， Fournier M.， Franck R.， Thouvenot R.， Inorg. Chem.， 1983， 22， 207—216
27	Liu H.， Gong L. G.，Wang C. X.， Wang C. M.， Yu K.， Zhou B. B.， J. Mater. Chem. A，2021， 9， 13161—13169
28	Augustyn V.， Come J.， Lowe M. A.， Kim J. W.， Taberna P. L.， Tolbert S. H.， Abruna H. D.， Simon P.， Dunn B.， Nat. Mater.， 2013， 12， 518—522
29	Wang J.， Polleux J.， Lim J.， Dunn B.， J. Phys. Chem. C， 2007， 111， 14925—14931
30	Chodankar N. R.， Dubal D. P.， Kwon Y.， Kim D. H.， NPG Asia Mater.， 2017， 9， e419
31	White A.， Slade R. C. T.， Syn. Metals， 2003， 139， 123—131
32	Skunik M.， Chojak M.， Rutkowska I. A.， Kulesza P. J.， Electrochim. Acta， 2008， 53， 3862—3869
33	Julien V.， Monica L. C.， Karina C. G.， Nieves C. P.， Pedro G. R.， Prog. Solid State Chem.， 2006， 34， 147—159

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Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid

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