Preparation and Electrochemical Properties of N-CNTs/NiCo-LDH Composite

doi:10.7503/cjcu20220351

Abstract

Abstract:

Nitrogen-doped carbon nanotubes（N-CNTs） were prepared by carbonizing polypyrrole nanotubes at high temperature， and nickel-cobalt layered double hydroxides（NiCo-LDH） were in situ grown on N-CNTs by coprecipitation method to produce N-CNTs/NiCo-LDH composite with three-dimensional interconnected network structure. The effect of different nickel/cobalt molar ratios on the morphology， structure and electrochemical properties of N-CNTs/NiCo-LDH composite was investigated. The results showed that N-CNTs/Ni₁Co₂-LDH had the best electrochemical performance when the molar ratio of nickel/cobalt was 1∶2. The specific capacitance can reach 1311.8 F/g at a current density of 1 A/g. When the current density was 10 A/g， the capacitance retention rate of N-CNTs/Ni₁Co₂-LDH was as high as 88.3%， showing excellent rate capability. After 2500 cycles， the capacitance retention rate of N-CNTs/Ni₁Co₂-LDH can still reach 76.4%， revealing good cycling stability. In addition， the N-CNTs/Ni₁Co₂-LDH//AC aqueous hybrid supercapacitor assembled by using N-CNTs/Ni₁Co₂-LDH and activated carbon（AC） electrodes had a high energy density of 27.19 W·h/kg at 750 W/kg power density. The exceptional electrochemical performance indicated that N-CNTs/Ni₁Co₂-LDH composite had broad application prospects in energy storage.

Key words: Nitrogen-doped carbon nanotubes, Nickel-cobalt layered double hydroxides, Electrode material, Electrochemical performance, Supercapacitor

CLC Number:

O646

TrendMD:

HOU Congcong, WANG Huiying, LI Tingting, ZHANG Zhiming, CHANG Chunrui, AN Libao. Preparation and Electrochemical Properties of N-CNTs/NiCo-LDH Composite[J]. Chem. J. Chinese Universities, 2022, 43(10): 20220351.

Figures/Tables 8

References 29

1	Hu C. L.， Zhang X.Y.， Liu B.， Chen S. Y.， Liu X. Q.， Liu Y. M.， Liu J. Y.， Chen J.， Electrochim. Acta， 2020， 338， 135846
2	Dubal D. P.， Chodankar N. R.， Caban⁃Huertas Z.， Wolfart F.， Vidotti M.， Holze R.， Lokhande C. D.， Gomez⁃Romero P.， J. Power Sources， 2016， 308， 158—165
3	Wan Y.， Song M. N.， Zhao M. T.， Chem. J. Chinese Universities， 2021， 42（2）， 575—594
	万月，宋美娜，赵美廷. 高等学校化学学报， 2021， 42（2）， 575—594
4	Niu H. T.， Zhang Y.， Liu Y.， Xin N.， Shi W. D.， J. Colloid Interf. Sci.， 2019， 539， 545—552
5	Yang W.， Ding Q. Y.， Zhai D. M.， Bo K. W.， Feng Y. Y.， Wen J.， He F.， Acta Phys. Sinica， 2022， 71（1）， 299—308
	杨文，丁倩瑶，翟冬梅，薄开雯，冯艳艳，文婕，何方. 物理学报， 2022， 71（1）， 299—308
6	Lamba P.， Singh P.， Singh P.， Singh P.， Bharti， Kumar A.， Gupta M.， Kumar Y.， J. Energy Storage， 2022， 48， 103871
7	Sun M. M.， Chang C. R.， Zhang Z. M.， An L. B.， Chem. J. Chinese Universities， 2019， 40（1）， 11—17
	孙蒙蒙，常春蕊，张志明，安立宝. 高等学校化学学报， 2019， 40（1）， 11—17
8	Dong S.， Li T. T.， Zhang Z. M.， Sun M. M.， An L. B.， Mater. Lett.， 2019， 253， 420—423
9	Zhao J. L.， Yang M.， Yang N. L.， Wang J. Y.， Wang D.， Chem. Res. Chinese Universities， 2020， 36（3）， 313—319
10	Jiang Q.， Chen J. K.， Chen Z.， He L. M.， Lu X. Y.， Hu A. L.， Chem. J. Chinese Universities， 2016， 37（1）， 73—78
	江奇，陈建康，陈姿，和腊梅，卢晓英，胡爱琳. 高等学校化学学报， 2016， 37（1）， 73—78
11	Mangisetti S. R.， Pari B.， Kamarej M.， Ramaprabhu S.， ChemSusChem， 2018， 11（10）， 1664—1677
12	Li X. Q.， Hao C. L.， Tang B. C.， Wang Y.， Liu M.， Wang Y. W.， Zhu Y. H.， Lu C. G.， Tang Z. Y.， Nanoscale， 2017， 9（6）， 2178—2187
13	Wei D. D.， Zhang Y. L.， Zhu X. Z.， Fan M. L.， Wang Y. L.， J. Alloy. Compd.， 2020， 824， 153937
14	Li M.， Cheng J. P.， Liu F.， Zhang X. B.， Chem. Phys. Lett.， 2015， 640， 5—10
15	Jiang L. Y.， Sui Y. W.， Qi J. Q.， Chang Y.， He Y. Z.， Meng Q. K.， Wei F. X.， Sun Z.， Jin Y. X.， Appl. Surf. Sci.， 2017， 426， 148—159
16	Li M.， Ma K. Y.， Cheng J. P.， Lv D. H.， Zhang X. B.， J. Power Sources， 2015， 286， 438—444
17	Yang F.， Chu J.， Cheng Y. P.， Gong J. F.， Wang X. Q.， Xiong S. X.， Chem. Res. Chinese Universities， 2021， 37（3）， 772—777
18	Chen T. T.， Lou L.， Wu X.， Zhou Y. L.， Yan W.， Fan M. Z.， Zhao W. G.， J. Alloy. Compd.， 2021， 859， 158318
19	Lai F. L.， Huang Y. P.， Miao Y.， Liu T. X.， Electrochim. Acta， 2015， 174， 456—463
20	Liu Q.， Pu Z. H.， Tang C.， Asiri A. M.， Qusti A. H.， Al⁃Youbi A. O.， Sun X. P.， Electrochem. Commun.， 2013，36，57—61
21	Dang T.， Wei D. H.， Zhang G. Q.， Wang L.， Li Q. G.， Liu H. Z.， Cao Z. Y.， Zhang G. H.， Duan H. G.， Electrochim. Acta， 2020， 341， 135988
22	Zhou L. L.， Lan C. L.， Xie R. G.， Yang Y. S.， Qin F. X.， J. Synth. Cryst.， 2020， 49（12）， 2331—2335
	周伶俐，兰翠玲，谢瑞刚，杨一松，秦冯详. 人工晶体学报， 2020， 49（12）， 2331—2335
23	Li M.， Liu F.， Cheng J. P.， Ying J.， Zhang X. B.， J. Alloy. Compd.， 2015， 635， 225—232
24	Wang D. H.， Chen Y.， Wang H. Q.， Zhao P. H.， Liu W.， Wang Y. Z.， Yang J. L.， Appl. Surf. Sci.， 2018， 457， 1018—1024
25	Liu R. H.， Wang Y. H.， Sun S. X.， Chen C. X.， Wu X. L.， Electroanal. Chem.， 2020， 878， 114571
26	Lv Z. J.， Zhong Q.， Bu Y. F.， Adv. Mater. Interfaces， 2018， 5（14）， 1800438
27	Zhang L. Y.， Cai P. F.， Wei Z. H.， Liu T.， Yu J. G.， Al⁃Ghamdi A. A.， Wageh S.， J. Colloid Interf. Sci.， 2021， 588， 637—645
28	Hou B. X.， Ma L. L.， Zang X. H.， Shang N. Z.， Song J. M.， Zhao X. X.， Wang C.， Qi J.， Wang J. Y.， Yu R. B.， Chem. Res. Chinese Universities， 2021， 37（2）， 265—273
29	Hao C.， Wang X. K.， Wu X. L.， Guo Y. N.， Zhu L. L.， Wang X. H.， Appl. Surf. Sci.， 2022， 572， 151373

[1]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.
[2]	WEI Yuchen, WU Tingting, YANG Lei, JIN Biyu, LI Hongqiang, HE Xiaojun. Preparation and Supercapacitive Performance of Naphthalene-based Interconnected Porous Carbon Nanocapsules [J]. Chem. J. Chinese Universities, 2021, 42(9): 2852.
[3]	BAO Junquan, ZHENG Shibing, YUAN Xuming, SHI Jinqiang, SUN Tianjiang, LIANG Jing. An Organic Salt PTO（KPD）₂ with Enhanced Performance as a Cathode Material in Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(9): 2911.
[4]	ZOU Junyan, ZHANG Yanyan, CHEN Shi, SHAO Huaiyu, TANG Yuxin. Recent Development on Surface-interface Chemistry of All-solid-state Lithium Batteries [J]. Chem. J. Chinese Universities, 2021, 42(4): 1005.
[5]	HUANG Dongxue, ZHANG Ying, ZENG Ting, ZHANG Yuanyuan, WAN Qijin, YANG Nianjun. Transition Metal Sulfides Hybridized with Reduced Graphene Oxide for High-Performance Supercapacitors [J]. Chem. J. Chinese Universities, 2021, 42(2): 643.
[6]	SHA Huiwen, MA Weiting, ZHOU Xiaojuan, SONG Weixing. One-step Preparation and Applications of Laser Induced Three-dimensional Reticular Graphene [J]. Chem. J. Chinese Universities, 2021, 42(2): 607.
[7]	CHEN Minghua, LI Hongwu, FAN He, LI Yu, LIU Weiduo, XIA Xinhui, CHEN Qingguo. Research Progress of Two-dimensional Transition Metal Dichalcogenides in Supercapacitors [J]. Chem. J. Chinese Universities, 2021, 42(2): 539.
[8]	ZHANG Weiguo, FAN Songhua, WANG Hongzhi, YAO Suwei. Synthesis of Self-assembled α-Fe₂O₃/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties [J]. Chem. J. Chinese Universities, 2020, 41(8): 1850.
[9]	XIANG Houzheng, XIE Hongxiang, LI Wenchao, LIU Xiaolei, MAO Aiqin, YU Haiyun. Synthesis and Electrochemical Performance of Spinel-type High-entropy Oxides [J]. Chem. J. Chinese Universities, 2020, 41(8): 1801.
[10]	GUAN Fanglan,LI Xin,ZHANG Qun,GONG Yan,LIN Ziyu,CHEN Yao,WANG Lejun. Fabrication and Capacitance Performance of Laser-machined RGO/MWCNT/CF In-plane Flexible Micro-supercapacitor ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 300.
[11]	LI Botian,SHAO Wei,XIAO Da,ZHOU Xue,DONG Junwei,TANG Liming. Polypyrrole Nanowire Gels Based on Templating Fabrication and Their Energy Storage and Electrochemical Sensing Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 183.
[12]	QIAN Ming,XU Zhimin,LIU Weiwei,HAN Bing. Preparation and Characterization of Pyrrole-(3,4-ethylenedioxythiophene) Copolymer Ordered Nanoarray Film^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 612.
[13]	LIU Ben,ZHANG Xingying,CHEN Shaoyun,HU Chenglong. Preparation and Electrochemical Energy Storage Performance of One Dimensional Orderly Polyaniline Nanowires Array^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 498.
[14]	LIU Hao,ZHAO Dingxuan,GONG Guodong,ZHANG Zhuxin,JIA Tuo,CHEN Hanzhe. Effect of Temperature on Morphology and Supercapacitor Performance of Carbon Nano-spheres^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 18.
[15]	LI Long,HU Hongli,DING Shujiang. Facile Synthesis of Scale-like CoMn₂O₄ Nanosheets on Reduced Graphene Oxide for Supercapacitors^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 2010.