高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (8): 1035.

• 研究论文 •    下一篇

含铁镍皂石的合成与交联的研究

孙铁1, 蒋大振1, 刘子阳1, 闵恩泽2, 付宏刚3   

  1. 1. 吉林大学化学系, 长春 130023;
    2. 北京石油化工科学研究院;
    3. 黑龙江大学化学系
  • 收稿日期:1992-09-08 修回日期:1993-01-20 出版日期:1993-08-24 发布日期:1993-08-24
  • 通讯作者: 孙铁.
  • 作者简介:第一作者:男, 30岁, 博士, 讲师.
  • 基金资助:

    中国石油化学工业总公司基金

Studies on Synthesis of Ferric Saponite and Ferric-Nickel Saponite and Cross-linking with Hydroxyl Aluminium

SUN Tie1, JIANG Da-Zhen1, LIU Zi-Yang1, MIN En-Ze2, FU Hong-Gang3   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023;
    2. Research Institute of Petroleum Processing, Beijing;
    3. Dept, of Chem., Heilongjiang Univ., Harbin
  • Received:1992-09-08 Revised:1993-01-20 Online:1993-08-24 Published:1993-08-24

PDF (PC)

被引次数

6

摘要： 用水热法合成出铁皂石和铁镍皂石,用羟基铝作交联剂制备了交联粘土.经XRD、DTA、IR、TPR、Mssbauer谱和化学分析表征,证明铁进入了粘土层骨架,铝交联可能作用在四面体铁上.形成Alp-O-Fe键.

关键词: 合成, 交联, Mossbauer谱, 皂石

Abstract: Ferric saponite and ferric-nickel saponite are synthesized by the hydrothermal method.Their cross-linking products are prepared with hydroxyl aleuminium oligomer.By the characterization with XRD, DTA, IR, TPR, Mossbauer spectra and chemical analysis, it is proved that iron exists in the framework of the synthesized clay.The position of cross-linking maybe locates on the tetrahedral iron with the formation of Alp-O-Fe bond.

Key words: Synthesis, Cross-linking, Mossbauer spectra, Saponite

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