高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (3): 305.

• 研究简报 • 上一篇    下一篇

TNT与α,β-不饱和醛反应产物的晶体结构

陈博仁, 冯增国, 刘佐才, 范广裕, 崔秀山   

  1. 北京理工大学化工系
  • 收稿日期:1988-11-30 出版日期:1990-03-24 发布日期:1990-03-24
  • 通讯作者: 陈博仁

The Crystal Structure of the Product from TNT with α,β-Unsaturated Aldehyde

Chen Boren, Feng Zengguo, Liu Zuocai, Fan Guangyu, Cui Xiushan   

  1. Department of Chemical Engineering, Beijing Institute of Technology, Beijing
  • Received:1988-11-30 Online:1990-03-24 Published:1990-03-24

PDF (PC)

摘要： 硝基喹啉-N-氧化物,通常采用几步反应合成[1.2],作者在研究2,4,6-三硝基甲苯(TNT)形成的硝基苄阴离子的反应活性过程中,发现一种由TNT和α,β-不饱和醛制备硝基喹啉-N-氧化物的简便方法。下面报道3-苯基-5,7-二硝基喹啉-N-氧化物的合成及晶体结构。

关键词: 硝基化合物, 喹啉-N-氧化物, 合成, 晶体结构

Abstract: 3-Phenyl-5,7-dinitroquinoline-N-oxide is synthesized from 2,4,6-trinitrotoluene with cin-namaldehyde and its crystal structure has been determined by single crystal X-ray diffraction. The single crystal belongs to a triclinic system, P1 space group, a = 6. 637(3) Å, b = 7. 646(3) Å, c=13. 823(8)Å, a=75.81(4)% 3=77.63(4)° ,γ=88. 38(4)°,V = 666. 5(5) Å3. Z = 2. Least-square refinement has led to a final Rvalue of 0.045.

Key words: Nitro compound, Quinoline-N-oxide, Synthesis, Crystal structure

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