高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (8): 797.

• 研究论文 • 上一篇    下一篇

Cr-ZSM-48和V-ZSM-48型分子筛的合成与结构

焦庆祝, 庞文琴   

  1. 吉林大学合成与催化研究所
  • 收稿日期:1988-11-14 出版日期:1990-08-24 发布日期:1990-08-24
  • 通讯作者: 焦庆祝(现在齐齐哈尔师范学院化学系)
  • 基金资助:

    国家自然科学基金

Syntheses and Structures of Cr-ZSM-48 and V-ZSM-48 Molecular Sieves

Jiao Qingzhu, Pang Wenqin   

  1. Institute of Synthetic and Catalytic Chemistry of Jilin University, Changchun
  • Received:1988-11-14 Online:1990-08-24 Published:1990-08-24

PDF (PC)

被引次数

14

摘要： 合成了新的Cr-ZSM-48型和V-ZSM-48型杂原子分子筛,并进行了结构表征,结果表明,Cr-ZSM-48、V-ZSM-48与全硅ZSM-48结构相同,Cr和V分别以+3和+4价态存在;杂原子以畸变四面体配位方式进入分子筛骨架。

关键词: 铬, 钒, ZSM-48型分子筛, 合成, 结构

Abstract: Cr-ZSM-48 and V-ZSM-48 type hetero-atom molecular sieves were synthesized and their structures were characterized by many physicochemical methods. The results show that Cr-ZSM-48, V-ZSM-48 and Silica-ZSM-48 are isostruclural. Cr and V exist as three-valence and four-valence ions respectively. The hetero-atoms are introduced into the framework of the molecular sieves in distortion-al tetrahedral coordination.

Key words: Chromium, Vanadium, ZSM-48, Systhesis, Structure

TrendMD: