高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (10): 1197.

• 论文 • 上一篇    下一篇

二邻巯基苯酚-苯甲酰肼合钼(Ⅳ)酸双三乙基亚铵三元固态配合物的合成及谱学特性

翟应离, 王修建, 王秋莹   

  1. 兰州大学化学系, 兰州, 730000
  • 收稿日期:1991-11-26 修回日期:1992-02-23 出版日期:1992-10-24 发布日期:1992-10-24
  • 通讯作者: 王秋莹

Syntheses and Spectroscopic Properties of Ternary Complex (这里有图片19921002-1197-1.gif)

ZHAI Ying-Li, WANG Xiu-Jian, WANG Qiu-Ying   

  1. Department of Chemistry, Lanzhou University, Lanzhou, 730000
  • Received:1991-11-26 Revised:1992-02-23 Online:1992-10-24 Published:1992-10-24

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摘要： 以(Bu4N)4Mo8O26为原料,以邻巯基苯酚和苯甲酰肼为配体,在甲醇中合成了未见报道的单核三元配合物二邻巯基苯酚-苯甲酰肼合钼(Ⅳ)酸双三乙基亚铵.通过元素分析、红外光谱、1H NMR谱、电子光谱、差热-热重分析对化合物的性质进行了表征,发现它是无端基氧钼配合物,并提出了其可能结构.

关键词: 钼配合物, 钼硫键, 钼氮键, 合成

Abstract: The ternary complex of monomolybdenum   was synthesized in methanol with o-mercaptophenol and benzoylhydrazine as the ligand and (Bu4N[Mo8O26] as the parent The properties of the complex were characterized by elemental analysis,molar conductivity,electronic spectra,infrared spectra,1H NMR spectra and TG-DTA,The most possible structure is proposed on the basis of the spectral data and the IR spectra show that the complex has not terminal oxygen atoms,

Key words: Molybdenum complex, Molybdenum-Sulfur bond, Molybdenum-Nitrogen bond, Synthesis

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