高等学校化学学报

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (7): 1309.

• 研究论文 • 上一篇    下一篇

三苄基和三丁基锡4-吡啶甲酸酯聚合物的合成、性质及晶体结构

尹汉东, 王传华, 王勇, 马春林   

  1. 聊城师范学院化学系, 聊城 252059
  • 收稿日期:2001-03-09 出版日期:2002-07-24 发布日期:2002-07-24
  • 通讯作者: 尹汉东(1956年出生),男,教授,主要从事金属有机化学研究.E-mail:yinhandong@263.net E-mail:yinhandong@263.net
  • 基金资助:

    教育部骨干教师基金;山东省自然科学基金(批准号:Q98B01117)

Synthesis and Crystal Structure of the Polymeric Tribenzyltin 4-Picolinate and Tributyltin 4-Picolinate

YIN Han-Dong, WANG Chuan-Hua, WANG Yong, MA Chun-Lin   

  1. Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059, China
  • Received:2001-03-09 Online:2002-07-24 Published:2002-07-24

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被引次数

28

摘要： 用三苄基氯化锡及三丁基氯化锡与4-吡啶甲酸钠反应,分别合成了三苄基锡4-吡啶甲酸酯(1)和三丁基锡-4-吡啶甲酸酯(2),并进行了红外光谱、核磁共振氢谱及质谱表征.X射线单晶衍射分析结果表明,化合物1属单斜晶系,P21/n空间群,晶胞参数:a=0.96564(8)nm,b=1.64085(14)nm,c=1.49403(13)nm,β=97.681(2)0,V=2.3460(3)nm3,Z=4,Dc=1.456g/cm3.化合物2属单斜晶系,P21/n空间群,晶胞参数:a=0.96673(14)nm,b=2.3845(4)nm,c=0.97071(14)nm,β=112.463(3)o,V=2.0679(5)nm3,Z=4,Dc=1.324g/cm3.两个化合物均通过4-吡啶甲酸配体的氮原子桥联,形成五配位三角双锥构型的一维无限链聚合物.

关键词: 一维无限链, 三烃基锡4-吡啶甲酸酯, 合成, 晶体结构

Abstract: Tribenzyltin 4-picolinate(1) and tributyltin 4-picolinate(2) were synthesized by the reaction of sodium 4 picolinate with the tribenzyltin chlorideor tributyltin chloride and were characterized by IR, 1H NMRand MS. Their crystal structures were determined by X-ray single crystal diffraction. The crystal 1 crystallizes in monoclinic, space group P21/n with a=0.96564(8) nm, b=1.64085(14) nm, c= 1.49403(13) nm, β =97.681(2)o, V=2.3460(3) nm3, Z=4, Dc=1.456 g/cm3, and crystal 2 in monoclinic, space group P2 1/c with a=0.96673(14) nm, b=2.3845(4) nm, c=0.97071(14) nm, β =112.463(3)o, V=2.0679(5) nm3, Z=4, Dc=1.324 g/cm3. In crystals 1 and 2, the tin atom rendered five coordinate in trigonal bipyramidal structure by bridging pyridine Natom and the resulted structures are one dimensional infinite chain polymer.

Key words: One-dimensional infinite chain, Trialkyltin 4-picolinate, Synthesis, Crystal structure

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