高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (1): 58.

• 研究论文 • 上一篇    下一篇

苯乙烯吡啶类化合物合成的新方法

汪志勇, 张祖德, 李前荣, 郭庆祥   

  1. 中国科学技术大学化学系, 合肥 230026
  • 收稿日期:2000-10-14 出版日期:2002-01-24 发布日期:2002-01-24
  • 通讯作者: 汪志勇(1962年出生),男,教授,从事钯催化的有机反应和有机磷化学研究.E-mail:zwang3@ustc.edu.cn E-mail:zwang3@ustc.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:50073021)资助

A Novel Method for the Syntheses of Stibazole Compounds

WANG Zhi-Yong, ZHANG Zu-De, LI Qian-Rong, GUO Qing-Xiang   

  1. Department of Chemistry, University of Science & Technology of China, Hefei 230026, China
  • Received:2000-10-14 Online:2002-01-24 Published:2002-01-24

摘要: 对Heck反应在苯乙烯吡啶类化合物合成中的应用进行了较为深入的研究,并提出了反应机理.采用改进的钯催化反应以高产率合成了一系列苯乙烯吡啶类化合物,为苯乙烯吡啶类化合物的制备提供了一种方便有效的新方法

关键词: 苯乙烯吡啶类化合物, 合成, 钯催化反应

Abstract: The application of Heck reaction to the preparation of stibazoles was investigated in detail. Also, the mechanism of the reaction in this situation was presented. Finally, a series of target compounds were synthesized by improved palladium-catalyzed reaction in excellent yields. Anovel, much efficient and convenient method for the preparation of stibazole compounds was afforded.

Key words: Stibazole compounds, Synthesis, Palladium catalyzed reaction

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