高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (3): 362.

• 研究快报 • 上一篇    下一篇

新型氨基酸-钨砷多金属氧酸盐K6[Cu(Ala)2·(H2O)2]2[Cu4(H2O)2(AsW9O34)2]·16H2O的合成与晶体结构

王永慧1, 胡长文1, 王恩波1, 胡宁海2, 贾恒庆2, 邢彦2   

  1. 1. 东北师范大学化学学院多酸化学研究所, 长春 130024;
    2. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:2000-07-03 出版日期:2001-03-24 发布日期:2001-03-24
  • 通讯作者: 胡长文(1955年出生),男,工学博士,教授,博士生导师,从事多酸化学研究.E-mail:huchw@nenu.edu.cn E-mail:huchw@nenu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:20071007);教育部青年骨干教师基金资助

Synthesis and Crystal Structure of a Novel Amino-acid-containing Polyoxometalate: K6[Cu(Ala)2(H2O)2]2[Cu4(H2O)2(AsW9O34 )2]·16H2O

WANG Yong-Hui1, HU Chang-Wen1, WANG En-Bo1, Hu-Ning-Hai2, Jia-Heng-Qing2, Xing-Yan2   

  1. 1. Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
    2. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022, China
  • Received:2000-07-03 Online:2001-03-24 Published:2001-03-24

PDF (PC)

关键词: 氨基酸, 钨砷多金属氧酸盐, 合成, 晶体结构

Abstract: The novel amino-acid-containing polyoxometalate K6[Cu(Ala)2(H2O)2]2[Cu4(H2O)2·(AsW9O34 )2]·16H2Owas synthesized from the reaction of K10 [Cu4(H2O)2(AsW9O34 )2]·20H2Owith β--alanine. Its structure has been determined by single crystal X-ray diffraction. It crystallizes in the triclinic space group P1, with a=1.1963(2) nm, b=1.5365(3) nm, c=1.5914(3) nm, α=93.97(3)°, β-=110.88(3)°, γ=101.07(3)°, V=2.6518(9) nm3 and Z=1. Least squares refinement of the structure leads to Rand Rw factors of 0.0673 and 0.1628, respectively. An unusual structural feature of the compound is that the polyanion [Cu4(H2O)2(AsW9O34 )2]10- is linked with the amino acid complex of Cu 2+ by a μ-oxygen atom.

Key words: Amino acid, Polyoxotungstoarsenate, Synthesis, Crystal structure

中图分类号: 

TrendMD: