高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (10): 1629.

• 研究简报 • 上一篇    下一篇

Keggin结构阳离子[AlO4Al12(OH)24(H2O)12]7+与杂多阴离子构筑的新型无机纳米簇凝胶

彭革, 胡长文, 陈立东, 王恩波   

  1. 东北师范大学化学学院多酸化学研究所, 长春 130024
  • 收稿日期:2000-09-18 出版日期:2001-10-24 发布日期:2001-10-24
  • 通讯作者: 胡长文(1955年出生),男,博士,教授,博士生导师,从事多酸化学研究.E-mail:huchw@nenu.edu.cn E-mail:huchw@nenu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:20071007);教育部骨干教师基金

Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO4Al12(OH)24(H2O)12]7+ and Heteropolyoxometalates

PENG Ge, HU Chang-Wen, CHEN Li-Dong, WANG En-Bo   

  1. Institute of Polyoxometalates Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
  • Received:2000-09-18 Online:2001-10-24 Published:2001-10-24

PDF (PC)

关键词: Keggin结构阳离子, 杂多阴离子, 合成, 结构表征, 凝胶

Abstract: The novel class of inorganic nanoclusters, [AlO4Al12(OH)24(H2O)12][SiW11039CoCl]·11H2O, [AlO4Al12(OH)24(H2O)12][P2W18062]Cl533H2Oand [AlO4Al12(OH)24(H2O)12]2[NaP5W30O110]·24H2O, consisting of Keggin cations and heteropolyoxometalates, has been synthesized and characterized by ICP, IRand NMR. It is proved that the intrinsic identities of Keggin cation and heteropolyanions of the clusters are preserved within the gels.

Key words: Keggintype cation, Heteropolyoxometalates, Synthesis, Structural characterization, Gel

中图分类号: 

TrendMD: