高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (4): 643.

• 论文 • 上一篇    下一篇

新型高效催化剂乙烯/1-丁烯气相齐聚和共聚制备弹性体及其结构与性能关系

胡锦民1, 王海华1, 麦堪成2   

  1. 1. 中山大学高分子化学研究所;
    2. 中山大学材料科学研究所, 广州 510275
  • 收稿日期:1999-04-06 出版日期:2000-04-24 发布日期:2000-04-24
  • 通讯作者: 王海华(1939年出生),男,教授,博士生导师,主要从事高分子化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29874039);]广东省自然科学基金

Relation Between Structure and Characteristics of Elastomers Prepared by Ethylene and 1-Butene Gas Oligamerization and Copolymerization with Highly Active Catalyst

HU Jin-Min1, WANG Hai-Hua1, MAI Kan-Cheng2   

  1. 1. Institute of Polymer Science;
    2. Materials Science Institute, Zhongshan University, Guangzhou 510275, China
  • Received:1999-04-06 Online:2000-04-24 Published:2000-04-24

PDF (PC)

被引次数

13

摘要： 用新型催化体系TiCl4,Ti(OBu)4/MgCl2,SiO2和ZnCl2/醇/AlR3催化乙烯与1-丁烯气相均聚及共聚,制得两种共聚物弹性体,发现新型催化剂体系具有独特的齐聚和原位共聚性能.采用13CNMR测定了共聚物链序列分布结构,观察到共聚单体在聚合物链中分布不均匀,存在较长的乙烯链段和较多的1-丁烯嵌段.产物DSC谱图表现出复杂的结晶熔融行为,存在多种结晶形态,出现熔融肩峰及双峰,与通常制得的LLDPE的结晶熔融行为有很大差别;结晶度和密度较低,并具有弹性体性质.

关键词: 齐聚, 共聚, 弹性体, 序列分布, 熔融行为

Abstract: Two elastomers have been prepared by gas copolymerization of ethylene and 1 butene with new highly active catalyst TiCl 4, Ti(OBu)4/MgCl 2, SiO2, ZnCl2/alcohol/AlR3. Triad sequence and comonomer distributions, average sequence length, run numbers are determined using13 C NMR. It was found that the new catalyst has the properties to catalyze ethylene and 1-butene oligamerization and copolymerization in situ . The distribution of comonomer 1-butene in copolymers is not homogeneous, and the content of [EBB] + [BBB] in triad sequence distribution of elastomer is higher than that of common LLDPE. The melting and crystallization behavior of products are investigated by the method of DSC. The products show complicated crystallization and melting behavior, and lower melting point, density and degree of crystallinity. These results can be attributed to the existence of more 1-butene blocks in the copolymers chain and their participation in crystallization. The crystallization in copolymers may be physical crosslinking points and the products display the properties of elastomer.

Key words: Oligamerization, Copolymerization, Elastomers, Sequence distribution, Melting behavior

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