高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (2): 246.

• 研究简报 • 上一篇    下一篇

三苯基锗不饱和烃基膦酸衍生物的合成和性质

尹汉东, 马春林, 张如芬, 王勇   

  1. 聊城师范学院化学系, 聊城 252059
  • 收稿日期:1999-05-05 出版日期:2000-02-24 发布日期:2000-02-24
  • 通讯作者: 马春林(1963年出生),男,博士,教授,从事金属有机化学研究.
  • 基金资助:

    山东省自然科学基金(批准号:Q98B01117)资助

Synthesis and Properties of Triphenylgermanium Derivatives of Unsaturated Alkylphosphonic Acid

YIN Han-Dong, MA Chun-Lin, ZHANG Ru-Fen, WANG Yong   

  1. Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059, China
  • Received:1999-05-05 Online:2000-02-24 Published:2000-02-24

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被引次数

15

关键词: 三苯基锗, 不饱和烃基膦酸, 合成, 生物活性

Abstract: Fourteen new triphenylgermanium derivatives of alkynyl or alkenyl phosphonic acid were synthesized by the reaction of corresponding triphenylgermanium chloride with alkynyl or alkenyl phosphates. All compounds were characterized by elemental analysis, IR, 1H NMRand MS. The results showed that bis(triphenylgermanium) alkynyl or alkenyl phosphonates are both four- and five-coordinated germanium and triphenylgermanium alkynyl or alkenyl phosphonates are five-coordinated germanium.

Key words: Triphenylgermanium, Unsaturated alkylphosphonic acid, Synthesis, Bioalogical activity

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