高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (3): 403.

• 论文 • 上一篇    下一篇

多氟烷氧基取代金属酞菁配合物的简便合成及其光谱特征

司玉贵, 龚跃法, 张正波   

  1. 华中理工大学化学系, 武汉 430074
  • 收稿日期:1998-06-08 出版日期:1999-03-24 发布日期:1999-03-24
  • 通讯作者: 龚跃法
  • 作者简介:司玉贵,男,24岁,硕士研究生.
  • 基金资助:

    湖北省自然科学基金(批准号:96J031)资助课题

Synthesis and Spectroscopic Characterizations of Polyfluoroalkoxy Chlorophthalocyanines

SI Yu-Gui, GONG Yue-Fa, ZHANG Zheng-Bo   

  1. Department of Chemistry, Huazhong University of Science and Technology, Wuhan, 430074
  • Received:1998-06-08 Online:1999-03-24 Published:1999-03-24

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被引次数

11

摘要： 制备了一些氯酞菁金属配合物,研究了它们与多氟醇盐的反应.结果表明,该反应可以方便地在氯酞菁环上引入多氟烷氧基.借此合成了一些多氟烷氧基取代金属酞菁配合物.产物经分离提纯后,用元素分析、IR、UV-Vis及19FNMR谱进行了表征,并观测了多氟烷氧基的引入对其脂溶性、热稳定性及电子光谱性质的影响.

关键词: 多氟金属酞菁配合物, 合成, 脂溶性, 热力学稳定性

Abstract: The preparation of some chlorophthalocyanines and the reactions of them with sodium polyfluoroalkoxide were reported in this paper. Some polyfluoroalkoxy chlorophthalocyanines have been obtained by this way, and characterized by elementary analysis, IR, UV-Vis, 19FNMR spectra after purification. The effects of introduction of polyfluoroalkoxy group in the ring on the solubility, thermodynamic stability and electronic spectra were also discussed.

Key words: Polyfluoroalkoxy chlorophthalocyanine, Synthesis, Liposolubility, Thermodynamic stability

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