高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (3): 385.

• 论文 • 上一篇    下一篇

双[N,N'-1,2-亚乙基-2,2'-(苯基亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]合双锰的合成、光谱特征及拟酶催化性能的研究

陈新斌, 朱申杰, 桂明德   

  1. 南开大学化学系, 天津, 300071
  • 收稿日期:1997-04-15 出版日期:1998-03-24 发布日期:1998-03-24
  • 通讯作者: 陈新斌,男,35岁,博士研究生.
  • 作者简介:陈新斌,男,35岁,博士研究生.
  • 基金资助:

    国家自然科学基金(批准号:29472055)资助课题.

The Studies of Synthesis and Spectral Characterization of Bis[N,N'-ethylene-2,2'-(phenylmethylene) bis(3,4-dimethylpyrrole-5-aldimino)]dimanganese and Biomimetic Catalytic Reaction

CHEN Xin-Bin, ZHU Shen-Jie, GUI Ming-De   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1997-04-15 Online:1998-03-24 Published:1998-03-24

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摘要： 首次报道了一个新的拟酶模型物--双[N,N'-1,2-亚乙基-2,2'-(苯基亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]合双锰的合成方法及光谱特征;并对用PhIO单加氧化环己烷反应的催化性能及自氧化反应进行了研究.结果表明,此Schiff碱双锰配合物的催化性能及稳定性与金属卟啉TPPMnCl相似.

关键词: Schiff碱, 合成, 模拟细胞色素, 单充氧化反应

Abstract: This paper first reports the synthesis and spectral characterization of bis [N,N'-ethylene 2,2'-(phenylmethylene)bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese as well as the biomimetic catalytic properties for the monooxygenation of cyclohexane with PhIO. The results show that the catalytic properties and stability of this binuclear manganese complex are similar to those of TPPMnCl and better than those of other Schiff base complexes known.

Key words: Schiff base, Synthesis, Mimicking cytochrome, Monooxidation

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