高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (6): 917.

• 研究简报 • 上一篇    下一篇

C60、C70与过氧苯甲酰反应的动力学研究

胡波, 薛万华, 张法义, 尚振锋, 马克勤, 臧雅茹, 赵学庄   

  1. 南开大学化学系, 天津 300071
  • 收稿日期:1995-07-03 出版日期:1996-06-24 发布日期:1996-06-24
  • 通讯作者: 赵学庄
  • 作者简介:胡波,男,25岁,硕士研究生.
  • 基金资助:

    国家自然科学基金

Studies on the Kinetics of the Reaction of C60 and C70 with Benzoyl Peroxide

HU Bo, XUE Wan-Hua, ZHANG Fa-Yi, SHANG Zhen-Feng, MA Ke-Qin, ZANG Ya-Ru, ZHAO Xue-Zhuang   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1995-07-03 Online:1996-06-24 Published:1996-06-24

关键词: C60, C70, 动力学

Abstract: The kinetics of the reaction of C60 and C70 with benzoyl peroxide is studied.The results show that the reaction is first order against fullerenes and the rate constants at 342.2K,348.2K, 353.2 Kand 358.2 Kwere calculated and they are in agreement with experimental results.The rate constant of C70 is greater than that of C60 and this indicated that C70is more actived than C60.The activation energies are 9.275×104J/mol and 8.438×104J/mol for C60 and C70 respectively.

Key words: C60, C70, Kinetics

TrendMD: